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学科主题: 氟化学
题名: Silver-Mediated Oxidative Trifluoromethylation of Phenols: Direct Synthesis of Aryl Trifluoromethyl Ethers
其他题名: 银参与酚的氧化三氟甲基化反应: 芳基三氟甲基醚的直接合成
作者: Liu JB(刘建波)1; Chen C(陈超)1; Chu LL(储玲玲)1; Chen ZH(陈增浩)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1
通讯作者: 卿凤翎
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201506329
卷: 54, 期:40, 页:11839-11842
收录类别: SCI
文章类型: 论文
英文摘要: Aryl trifluoromethyl ethers (ArOCF3) are prevalent in pharmaceuticals, agrochemicals, and materials. However, methods for the general and efficient synthesis of these compounds are extremely underdeveloped and limited. Herein, we describe a highly efficient and general procedure for the direct O-trifluoromethylation of unprotected phenols through a silver-mediated cross-coupling reaction using CF3SiMe3 as the CF3 source and exogenous oxidants. This novel oxidative trifluoromethylation provides access to a wide range of aryl trifluoromethyl ethers from simple phenols. The mild process was also applied to the late-stage trifluoromethylation of a medicinally relevant compound.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000363394800045
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39750
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.东华大学

Recommended Citation:
Liu JB,Chen C,Chu LL,et al. Silver-Mediated Oxidative Trifluoromethylation of Phenols: Direct Synthesis of Aryl Trifluoromethyl Ethers[J]. Angew. Chem.-Int. Edit.,2015,54(40):11839-11842.
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