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Synthesis of trifluoromethylated compounds from alcohols via alkoxydiphenylphosphines
Alternative Title通过烷氧基二苯基膦由醇合成三氟甲基化合物
Li JL(李俊力); Yang XJ(杨先金); Wang YN(王亚南); Liu JT(刘金涛)
Source PublicationJ. Fluor. Chem.
AbstractThe transformation of hydroxyl group in benzyl or allyl alcohols to trifluoromethyl was achieved via the reaction of the corresponding alkyloxydiphenylphosphine and CuCF3, generated in situ from methyl fluorosulfonyldifluoroacetate and CuI, under mild conditions. A plausible mechanism was proposed on the basis of experimental results. (C) 2015 Elsevier B.V. All rights reserved.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000362929600036
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Document Type期刊论文
Corresponding AuthorLiu JT(刘金涛)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Li JL,Yang XJ,Wang YN,et al. Synthesis of trifluoromethylated compounds from alcohols via alkoxydiphenylphosphines[J]. J. Fluor. Chem.,2015,178:254-259.
APA 李俊力,杨先金,王亚南,&刘金涛.(2015).Synthesis of trifluoromethylated compounds from alcohols via alkoxydiphenylphosphines.J. Fluor. Chem.,178,254-259.
MLA 李俊力,et al."Synthesis of trifluoromethylated compounds from alcohols via alkoxydiphenylphosphines".J. Fluor. Chem. 178(2015):254-259.
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