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学科主题: 氟化学
题名: Synthesis of trifluoromethylated compounds from alcohols via alkoxydiphenylphosphines
其他题名: 通过烷氧基二苯基膦由醇合成三氟甲基化合物
作者: Li JL(李俊力); Yang XJ(杨先金); Wang YN(王亚南); Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: J. Fluor. Chem.
发表日期: 2015
DOI: 10.1016/j.jfluchem.2015.08.011
卷: 178, 页:254-259
收录类别: SCI
文章类型: 论文
英文摘要: The transformation of hydroxyl group in benzyl or allyl alcohols to trifluoromethyl was achieved via the reaction of the corresponding alkyloxydiphenylphosphine and CuCF3, generated in situ from methyl fluorosulfonyldifluoroacetate and CuI, under mild conditions. A plausible mechanism was proposed on the basis of experimental results. (C) 2015 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000362929600036
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39749
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Li JL,Yang XJ,Wang YN,et al. Synthesis of trifluoromethylated compounds from alcohols via alkoxydiphenylphosphines[J]. J. Fluor. Chem.,2015,178:254-259.
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