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学科主题: 氟化学
题名: Silver-Mediated Oxidative Trifluoromethylation of Alcohols to Alkyl Trifluoromethyl Ethers
其他题名: 银参与醇的氧化三氟甲基反应生成烷基三氟甲基醚
作者: Liu JB(刘建波)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1
通讯作者: 卿凤翎
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/acs.orglett.5b02522
卷: 17, 期:20, 页:5048-5051
收录类别: SCI
文章类型: 论文
英文摘要: The development of an efficient and practical method for the preparation of alkyl trifluoromethyl ethers is urgently demanding. The silver-mediated oxidative O-trifluoromethylation of primary, secondary, and tertiary alcohols with TMSCF3 under mild reaction conditions is established to provide a novel approach to a broad range of alkyl trifluoromethyl ethers. Further, this method is applied to the late-stage O-trifluoromethylation of complex natural products and prescribed pharmaceutical agents.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000363225000030
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39748
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.东华大学

Recommended Citation:
Liu JB,Xu XH,Qing FL. Silver-Mediated Oxidative Trifluoromethylation of Alcohols to Alkyl Trifluoromethyl Ethers[J]. Org. Lett.,2015,17(20):5048-5051.
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