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学科主题: 氟化学
题名: Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes
其他题名: 以双芳基碘(III)盐催化的芳炔氟化来合成邻氟代碘代芳烃
作者: Ceng YW(曾裕文); Li GY(李光玉); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201503308
卷: 54, 期:37, 页:10773-10777
收录类别: SCI
文章类型: 论文
英文摘要: Described is a one-pot vicinal fluorination-iodination of arynes at room temperature. The diphenyliodonium salt proved to be a privileged catalyst for this nucleophilic fluorination process using CsF as a fluorine source, and a subsequent facile electrophilic iodination with C4F9I was also found to be crucial to ensure the efficient fluorination. This new synthetic protocol has a broad substrate scope under mild reaction conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000360628500009
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39743
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Ceng YW,Li GY,Hu JB. Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes[J]. Angew. Chem.-Int. Edit.,2015,54(37):10773-10777.
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