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Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes
Alternative Title以双芳基碘(III)盐催化的芳炔氟化来合成邻氟代碘代芳烃
Ceng YW(曾裕文); Li GY(李光玉); Hu JB(胡金波)
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:37Pages:10773-10777
AbstractDescribed is a one-pot vicinal fluorination-iodination of arynes at room temperature. The diphenyliodonium salt proved to be a privileged catalyst for this nucleophilic fluorination process using CsF as a fluorine source, and a subsequent facile electrophilic iodination with C4F9I was also found to be crucial to ensure the efficient fluorination. This new synthetic protocol has a broad substrate scope under mild reaction conditions.
Subtype论文
Subject Area氟化学
DOI10.1002/anie.201503308
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000360628500009
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39743
Collection中科院有机氟化学重点实验室
Corresponding AuthorHu JB(胡金波)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Ceng YW,Li GY,Hu JB. Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes[J]. Angew. Chem.-Int. Edit.,2015,54(37):10773-10777.
APA 曾裕文,李光玉,&胡金波.(2015).Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes.Angew. Chem.-Int. Edit.,54(37),10773-10777.
MLA 曾裕文,et al."Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes".Angew. Chem.-Int. Edit. 54.37(2015):10773-10777.
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