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学科主题: 氟化学
题名: N-Difluoromethylthiophthalimide: A Shelf-Stable, Electrophilic Reagent for Difluoromethylthiolation
其他题名: N-二氟甲硫基邻苯酰亚胺: 一个稳定的亲电二氟甲硫基试剂
作者: Zhu DH(朱佃虎); Gu Y(古阳); Lv L(吕龙); Shen QL(沈其龙)
通讯作者: 吕龙 ; 沈其龙
刊名: J. Am. Chem. Soc.
发表日期: 2015
DOI: 10.1021/jacs.5b03170
卷: 137, 期:33, 页:10547-10553
收录类别: SCI
文章类型: 论文
英文摘要: A new, electrophilic difluoromethylthiolating reagent N-difluoromethylthiophthalimide 3 was developed. Reagent 3 can be readily synthesized in four steps from easily available starting materials phthalimide and TMSCF2H. N-difluoromethylthiophthalimide 3 is a powerful electrophilic difluoromethylthiolating reagent that allows the difluoromethylthiolation of a wide range of nucleophiles including aryl/vinyl boronic acids, alkynes, amines, thiols, beta-ketoesters, and oxindoles and electron-rich heteroarenes such as indole, pyrrole, 1H-pyrrolo[2,3-b]pyridine, imidazo[1,2-a]pyridine, aminothiazole, isoxazole, and pyrazole under mild conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000360321100025
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39742
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Zhu DH,Gu Y,Lv L,et al. N-Difluoromethylthiophthalimide: A Shelf-Stable, Electrophilic Reagent for Difluoromethylthiolation[J]. J. Am. Chem. Soc.,2015,137(33):10547-10553.
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