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Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3
Alternative Title铜参与芳基重氮盐与NaSO2CF3的三氟甲磺酰化和三氟甲基化反应
Zhang K(张柯)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1
2015
Source PublicationJ. Org. Chem.
Volume80Issue:15Pages:7658-7665
AbstractA tunable chemoselective trifluoromethanesulfonylation and trifluoromethylation of arenediazonium tetrafluoroborates with Langlois' reagent (NaSO2CF3) was developed. The Cu2O-catalyzed reaction in DMSO gave aryl trifluoromethanesulfones as the major products. On the other hand, the trifluoromethylated arenes were produced in the presence of oxidant tert-butyl hydroperoxide, CuBF4(MeCN)(4), and 2,2';6',2 ''-terpyridine (tpy). Both of these transformations proceed under mild conditions and tolerate functional groups.
Subtype论文
Subject Area氟化学
DOI10.1021/acs.joc.5b01295
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000359393500037
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39739
Collection中科院有机氟化学重点实验室
Corresponding AuthorXu XH(徐修华); Qing FL(卿凤翎)
Affiliation1.东华大学
2.中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Zhang K,Xu XH,Qing FL. Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3[J]. J. Org. Chem.,2015,80(15):7658-7665.
APA 张柯,徐修华,&卿凤翎.(2015).Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3.J. Org. Chem.,80(15),7658-7665.
MLA 张柯,et al."Copper-Promoted Trifluoromethanesulfonylation and Trifluoromethylation of Arenediazonium Tetrafluoroborates with NaSO2CF3".J. Org. Chem. 80.15(2015):7658-7665.
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