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Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions
其他题名碳氢键三氟甲硫基化与三氟甲氧基化的最新进展
Lin JH(林锦鸿); Ji YL(季云龙); Xiao JC(肖吉昌)
2015
发表期刊Curr. Org. Chem.
卷号19期号:16页码:1541-1553
摘要As both trifluoromethylthio (CF3S) and trifluoromethoxy (CF3O) moieties have proved to be valuable functionalities in pharmaceutical chemistry, trifluoromethylthiolation and trifluoromethoxylation have received a great deal of attention. For the trifluoromethylthiolation reaction, a variety of efficient methods have been developed. Among these methods, C-H trifluoromethylthiolation avoids the need to prefunctionalize substrates, meaning that this straightforward protocol is quite attractive and promising. The first section of this review summarizes recent advances in this field, including Csp(3)-H, Csp(2)-H and Csp-H trifluoromethylthiolation and the asymmetric Csp(3)-H trifluoromethylthiolation reactions. Trifluoromethoxylation with safe trifluoromethoxylation reagents remains a significant challenge. The second section of this review summarizes the recent progress in trifluoromethoxylation reaction.
文章类型论文
学科领域氟化学
DOI10.2174/1385272819666150520230727
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收录类别SCI
语种英语
WOS记录号WOS:000358962300003
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39736
专题中科院有机氟化学重点实验室
通讯作者Lin JH(林锦鸿); Xiao JC(肖吉昌)
作者单位中科院上海有机化学研究所, 有机氟化学重点实验室
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Lin JH,Ji YL,Xiao JC. Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions[J]. Curr. Org. Chem.,2015,19(16):1541-1553.
APA 林锦鸿,季云龙,&肖吉昌.(2015).Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions.Curr. Org. Chem.,19(16),1541-1553.
MLA 林锦鸿,et al."Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions".Curr. Org. Chem. 19.16(2015):1541-1553.
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