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Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions
Alternative Title碳氢键三氟甲硫基化与三氟甲氧基化的最新进展
Lin JH(林锦鸿); Ji YL(季云龙); Xiao JC(肖吉昌)
2015
Source PublicationCurr. Org. Chem.
Volume19Issue:16Pages:1541-1553
AbstractAs both trifluoromethylthio (CF3S) and trifluoromethoxy (CF3O) moieties have proved to be valuable functionalities in pharmaceutical chemistry, trifluoromethylthiolation and trifluoromethoxylation have received a great deal of attention. For the trifluoromethylthiolation reaction, a variety of efficient methods have been developed. Among these methods, C-H trifluoromethylthiolation avoids the need to prefunctionalize substrates, meaning that this straightforward protocol is quite attractive and promising. The first section of this review summarizes recent advances in this field, including Csp(3)-H, Csp(2)-H and Csp-H trifluoromethylthiolation and the asymmetric Csp(3)-H trifluoromethylthiolation reactions. Trifluoromethoxylation with safe trifluoromethoxylation reagents remains a significant challenge. The second section of this review summarizes the recent progress in trifluoromethoxylation reaction.
Subtype论文
Subject Area氟化学
DOI10.2174/1385272819666150520230727
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000358962300003
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39736
Collection中科院有机氟化学重点实验室
Corresponding AuthorLin JH(林锦鸿); Xiao JC(肖吉昌)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Lin JH,Ji YL,Xiao JC. Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions[J]. Curr. Org. Chem.,2015,19(16):1541-1553.
APA 林锦鸿,季云龙,&肖吉昌.(2015).Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions.Curr. Org. Chem.,19(16),1541-1553.
MLA 林锦鸿,et al."Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions".Curr. Org. Chem. 19.16(2015):1541-1553.
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