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学科主题: 氟化学
题名: Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions
其他题名: 碳氢键三氟甲硫基化与三氟甲氧基化的最新进展
作者: Lin JH(林锦鸿); Ji YL(季云龙); Xiao JC(肖吉昌)
通讯作者: 林锦鸿 ; 肖吉昌
刊名: Curr. Org. Chem.
发表日期: 2015
DOI: 10.2174/1385272819666150520230727
卷: 19, 期:16, 页:1541-1553
收录类别: SCI
文章类型: 论文
英文摘要: As both trifluoromethylthio (CF3S) and trifluoromethoxy (CF3O) moieties have proved to be valuable functionalities in pharmaceutical chemistry, trifluoromethylthiolation and trifluoromethoxylation have received a great deal of attention. For the trifluoromethylthiolation reaction, a variety of efficient methods have been developed. Among these methods, C-H trifluoromethylthiolation avoids the need to prefunctionalize substrates, meaning that this straightforward protocol is quite attractive and promising. The first section of this review summarizes recent advances in this field, including Csp(3)-H, Csp(2)-H and Csp-H trifluoromethylthiolation and the asymmetric Csp(3)-H trifluoromethylthiolation reactions. Trifluoromethoxylation with safe trifluoromethoxylation reagents remains a significant challenge. The second section of this review summarizes the recent progress in trifluoromethoxylation reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000358962300003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39736
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Lin JH,Ji YL,Xiao JC. Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions[J]. Curr. Org. Chem.,2015,19(16):1541-1553.
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