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Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation
Alternative Title非对映选择性的Johnson-Corey-Chaykovsky三氟亚乙基化反应
Duan YY(段亚亚); Zhou B(周斌); Lin JH(林锦鸿); Xiao JC(肖吉昌)
Source PublicationChem. Commun.
Abstract(2,2,2-Trifluoroethyl)diphenylsulfonium triflate was found to be an efficient ylide reagent for the Johnson-Corey-Chaykovsky reaction to afford trifluoromethyl epoxides, cyclopropanes and aziridines. Interestingly, excellent but different diastereoselectivity was observed for these transformations. Both trifluoromethyl epoxides and cyclopropanes were obtained with trans-selectivity, whereas aziridines were obtained with cis-selectivity.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000359151100017
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Document Type期刊论文
Corresponding AuthorXiao JC(肖吉昌)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Duan YY,Zhou B,Lin JH,et al. Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation[J]. Chem. Commun.,2015,51(66):13127-13130.
APA 段亚亚,周斌,林锦鸿,&肖吉昌.(2015).Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation.Chem. Commun.,51(66),13127-13130.
MLA 段亚亚,et al."Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation".Chem. Commun. 51.66(2015):13127-13130.
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