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学科主题: 氟化学
题名: Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation
其他题名: 非对映选择性的Johnson-Corey-Chaykovsky三氟亚乙基化反应
作者: Duan YY(段亚亚); Zhou B(周斌); Lin JH(林锦鸿); Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Chem. Commun.
发表日期: 2015
DOI: 10.1039/c5cc04991a
卷: 51, 期:66, 页:13127-13130
收录类别: SCI
文章类型: 论文
英文摘要: (2,2,2-Trifluoroethyl)diphenylsulfonium triflate was found to be an efficient ylide reagent for the Johnson-Corey-Chaykovsky reaction to afford trifluoromethyl epoxides, cyclopropanes and aziridines. Interestingly, excellent but different diastereoselectivity was observed for these transformations. Both trifluoromethyl epoxides and cyclopropanes were obtained with trans-selectivity, whereas aziridines were obtained with cis-selectivity.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000359151100017
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39735
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Duan YY,Zhou B,Lin JH,et al. Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation[J]. Chem. Commun.,2015,51(66):13127-13130.
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