SIOC OpenIR  > 中科院有机氟化学重点实验室
Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation
Alternative Title非对映选择性的Johnson-Corey-Chaykovsky三氟亚乙基化反应
Duan YY(段亚亚); Zhou B(周斌); Lin JH(林锦鸿); Xiao JC(肖吉昌)
2015
Source PublicationChem. Commun.
Volume51Issue:66Pages:13127-13130
Abstract(2,2,2-Trifluoroethyl)diphenylsulfonium triflate was found to be an efficient ylide reagent for the Johnson-Corey-Chaykovsky reaction to afford trifluoromethyl epoxides, cyclopropanes and aziridines. Interestingly, excellent but different diastereoselectivity was observed for these transformations. Both trifluoromethyl epoxides and cyclopropanes were obtained with trans-selectivity, whereas aziridines were obtained with cis-selectivity.
Subtype论文
Subject Area氟化学
DOI10.1039/c5cc04991a
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000359151100017
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39735
Collection中科院有机氟化学重点实验室
Corresponding AuthorXiao JC(肖吉昌)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Duan YY,Zhou B,Lin JH,et al. Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation[J]. Chem. Commun.,2015,51(66):13127-13130.
APA 段亚亚,周斌,林锦鸿,&肖吉昌.(2015).Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation.Chem. Commun.,51(66),13127-13130.
MLA 段亚亚,et al."Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation".Chem. Commun. 51.66(2015):13127-13130.
Files in This Item:
File Name/Size DocType Version Access License
2015408.pdf(1707KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[段亚亚]'s Articles
[周斌]'s Articles
[林锦鸿]'s Articles
Baidu academic
Similar articles in Baidu academic
[段亚亚]'s Articles
[周斌]'s Articles
[林锦鸿]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[段亚亚]'s Articles
[周斌]'s Articles
[林锦鸿]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.