SIOC OpenIR  > 中科院有机氟化学重点实验室
Facile Access to Fluoromethylated Arenes by Nickel-Catalyzed Cross-Coupling between Arylboronic Acids and Fluoromethyl Bromide
Alternative Title镍催化下芳基硼酸与氟溴甲烷的偶联反应
An L(安伦); Xiao YL(肖玉兰); Min QQ(闵巧桥); Zhang XG(张新刚)
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:31Pages:9079-9083
AbstractThe nickel-catalyzed fluoromethylation of arylboronic acids was achieved with the industrial raw material fluoromethyl bromide (CH2FBr) as the coupling partner. The reaction proceeded under mild reaction conditions with high efficiency; it features the use of a low-cost nickel catalyst, synthetic simplicity, and excellent functional-group compatibility, and provides facile access to fluoromethylated biologically relevant molecules. Preliminary mechanistic studies showed that a single-electron-transfer (SET) pathway is involved in the catalytic cycle.
Subtype论文
Subject Area氟化学
DOI10.1002/anie.201502882
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000358501500038
Citation statistics
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39734
Collection中科院有机氟化学重点实验室
Corresponding AuthorZhang XG(张新刚)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
An L,Xiao YL,Min QQ,et al. Facile Access to Fluoromethylated Arenes by Nickel-Catalyzed Cross-Coupling between Arylboronic Acids and Fluoromethyl Bromide[J]. Angew. Chem.-Int. Edit.,2015,54(31):9079-9083.
APA 安伦,肖玉兰,闵巧桥,&张新刚.(2015).Facile Access to Fluoromethylated Arenes by Nickel-Catalyzed Cross-Coupling between Arylboronic Acids and Fluoromethyl Bromide.Angew. Chem.-Int. Edit.,54(31),9079-9083.
MLA 安伦,et al."Facile Access to Fluoromethylated Arenes by Nickel-Catalyzed Cross-Coupling between Arylboronic Acids and Fluoromethyl Bromide".Angew. Chem.-Int. Edit. 54.31(2015):9079-9083.
Files in This Item:
File Name/Size DocType Version Access License
2015371.pdf(696KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[安伦]'s Articles
[肖玉兰]'s Articles
[闵巧桥]'s Articles
Baidu academic
Similar articles in Baidu academic
[安伦]'s Articles
[肖玉兰]'s Articles
[闵巧桥]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[安伦]'s Articles
[肖玉兰]'s Articles
[闵巧桥]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.