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学科主题: 氟化学
题名: Facile Access to Fluoromethylated Arenes by Nickel-Catalyzed Cross-Coupling between Arylboronic Acids and Fluoromethyl Bromide
其他题名: 镍催化下芳基硼酸与氟溴甲烷的偶联反应
作者: An L(安伦); Xiao YL(肖玉兰); Min QQ(闵巧桥); Zhang XG(张新刚)
通讯作者: 张新刚
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201502882
卷: 54, 期:31, 页:9079-9083
收录类别: SCI
文章类型: 论文
英文摘要: The nickel-catalyzed fluoromethylation of arylboronic acids was achieved with the industrial raw material fluoromethyl bromide (CH2FBr) as the coupling partner. The reaction proceeded under mild reaction conditions with high efficiency; it features the use of a low-cost nickel catalyst, synthetic simplicity, and excellent functional-group compatibility, and provides facile access to fluoromethylated biologically relevant molecules. Preliminary mechanistic studies showed that a single-electron-transfer (SET) pathway is involved in the catalytic cycle.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000358501500038
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39734
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
An L,Xiao YL,Min QQ,et al. Facile Access to Fluoromethylated Arenes by Nickel-Catalyzed Cross-Coupling between Arylboronic Acids and Fluoromethyl Bromide[J]. Angew. Chem.-Int. Edit.,2015,54(31):9079-9083.
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