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学科主题: 氟化学
题名: Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin
其他题名: 铑催化下多氟芳烃邻位选择性C-F键硼化
作者: Guo WH(郭文豪); Min QQ(闵巧桥); Gu JW(顾继伟); Zhang XG(张新刚)
通讯作者: 张新刚
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201500124
卷: 54, 期:31, 页:9075-9078
收录类别: SCI
文章类型: 论文
英文摘要: An ortho-selective CF bond borylation between N-heterocycle-substituted polyfluoroarenes and Bpin-Bpin with simple and commercially available [Rh(cod)(2)]BF4 as a catalyst is now reported. The reaction proceeds under mild reaction conditions with high efficiency and broad substrate scope, even toward monofluoroarene, thus providing a facile access to a wide range of borylated fluoroarenes that are useful for photoelectronic materials. Preliminary mechanistic studies reveal that a Rh-III/V catalytic cycle via a key intermediate rhodium(III) hydride complex [(H)(RhLn)-L-III(Bpin)] may be involved in the reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000358501500037
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39733
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Guo WH,Min QQ,Gu JW,et al. Rhodium-Catalyzed ortho-Selective C-F Bond Borylation of Polyfluoroarenes with Bpin-Bpin[J]. Angew. Chem.-Int. Edit.,2015,54(31):9075-9078.
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