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Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation
Alternative TitleWell-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation
Gu Y(古阳)1; Chang DL(常大路)1; Leng XB(冷雪冰)1; Gu YC(顾玉成)1; Shen QL(沈其龙)1
Source PublicationOrganometallics
AbstractThe preparation of the thermally stable, well-defined NHC-ligated difluoromethylated silver complexes la,b is described. The complexes were fully characterized, and the structural assignments were ambiguously further confirmed by single-crystal X-ray diffraction. Reactions of [(SIPr)Ag(CF2H)] with a variety of activated electrophiles such as diaryliodonium salts, vinyl(aryl)iodonium salts, aryldiazonium salts, and acid chlorides in the presence or absence of CuI occurred smoothly at room temperature to generate difluoromethylated compounds in good to excellent yields.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000356903100042
Citation statistics
Cited Times:40[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorShen QL(沈其龙)
Affiliation1.中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Gu Y,Chang DL,Leng XB,et al. Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation[J]. Organometallics,2015,34(12):3065-3071.
APA 古阳,常大路,冷雪冰,顾玉成,&沈其龙.(2015).Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation.Organometallics,34(12),3065-3071.
MLA 古阳,et al."Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation".Organometallics 34.12(2015):3065-3071.
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