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学科主题: 氟化学
题名: Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation
其他题名: Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation
作者: Gu Y(古阳)1; Chang DL(常大路)1; Leng XB(冷雪冰)1; Gu YC(顾玉成)1; Shen QL(沈其龙)1
通讯作者: 沈其龙
刊名: Organometallics
发表日期: 2015
DOI: 10.1021/acs.organomet.5b00350
卷: 34, 期:12, 页:3065-3071
收录类别: SCI
文章类型: 论文
英文摘要: The preparation of the thermally stable, well-defined NHC-ligated difluoromethylated silver complexes la,b is described. The complexes were fully characterized, and the structural assignments were ambiguously further confirmed by single-crystal X-ray diffraction. Reactions of [(SIPr)Ag(CF2H)] with a variety of activated electrophiles such as diaryliodonium salts, vinyl(aryl)iodonium salts, aryldiazonium salts, and acid chlorides in the presence or absence of CuI occurred smoothly at room temperature to generate difluoromethylated compounds in good to excellent yields.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000356903100042
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39730
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.英国先正达

Recommended Citation:
Gu Y,Chang DL,Leng XB,et al. Well-Defined, Shelf-Stable (NHC)Ag(CF2H) Complexes for Difluoromethylation[J]. Organometallics,2015,34(12):3065-3071.
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