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Trifluoromethyl-Substituted Sulfonium Ylide: Rh-Catalyzed Carbenoid Addition to Trifluoromethylthioether
Alternative Title三氟甲基取代的锍叶立德: 铑催化卡宾与三氟甲基硫醚的加成
Liu YF(刘亚飞); Shao XX(邵欣欣); Zhang PP(张盼盼); Lv L(吕龙); Shen QL(沈其龙)
Source PublicationOrg. Lett.
AbstractA highly efficient Rh-catalyzed carbenoid addition to trifluoromethylthioether for the formation of trifluoromethyl-substituted sulfonium ylide is described. The trifluoromethyl-substituted sulfonium ylide can act as an electrophilic trifluoromethylation reagent, as demonstrated by trifluoromethylation of beta-ketoesters and aryl iodides.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000355962200048
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Document Type期刊论文
Corresponding AuthorLv L(吕龙); Shen QL(沈其龙)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Liu YF,Shao XX,Zhang PP,et al. Trifluoromethyl-Substituted Sulfonium Ylide: Rh-Catalyzed Carbenoid Addition to Trifluoromethylthioether[J]. Org. Lett.,2015,17(11):2752-2755.
APA 刘亚飞,邵欣欣,张盼盼,吕龙,&沈其龙.(2015).Trifluoromethyl-Substituted Sulfonium Ylide: Rh-Catalyzed Carbenoid Addition to Trifluoromethylthioether.Org. Lett.,17(11),2752-2755.
MLA 刘亚飞,et al."Trifluoromethyl-Substituted Sulfonium Ylide: Rh-Catalyzed Carbenoid Addition to Trifluoromethylthioether".Org. Lett. 17.11(2015):2752-2755.
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