| Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes | |
| Alternative Title | 银参与未活化烯烃的氧化三氟甲基化反应 |
| Yu W(余伟)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1 | |
| 2015 | |
| Source Publication | Adv. Synth. Catal.
 |
| Volume | 357Issue:9Pages:2039-2044 |
| Abstract | An efficient regioselective fluorotrifluoro-methylation of unactivated alkenes has been developed. The reaction of alkenes with (trifluoromethyl) trimethylsilane (TMSCF3) and Selectfluor in the presence of silver trifluoromethanesulfonate (AgOTf), cesium fluoride (CsF), and iodobenzene diacetate [PhI(OAc)(2)] in N,N-dimethylformamide (DMF) at -20 degrees C gave the corresponding fluorotrifluoromethylated products in moderate to good yields. The silver salt turns out to be crucial for this transformation. |
| Subtype | 论文 |
| Subject Area | 氟化学 |
| DOI | 10.1002/adsc.201500027 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000356373200008 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/39728 |
| Collection | 中科院有机氟化学重点实验室 |
| Corresponding Author | Qing FL(卿凤翎) |
| Affiliation | 1.中科院上海有机化学研究所, 有机氟化学重点实验室 2.东华大学 |
| Recommended Citation GB/T 7714 | Yu W,Xu XH,Qing FL. Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes[J]. Adv. Synth. Catal.,2015,357(9):2039-2044. |
| APA | 余伟,徐修华,&卿凤翎.(2015).Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes.Adv. Synth. Catal.,357(9),2039-2044. |
| MLA | 余伟,et al."Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes".Adv. Synth. Catal. 357.9(2015):2039-2044. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015309.pdf（356KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | Application Full Text | |
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