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学科主题: 氟化学
题名: Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes
其他题名: 银参与未活化烯烃的氧化三氟甲基化反应
作者: Yu W(余伟)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1
通讯作者: 卿凤翎
刊名: Adv. Synth. Catal.
发表日期: 2015
DOI: 10.1002/adsc.201500027
卷: 357, 期:9, 页:2039-2044
收录类别: SCI
文章类型: 论文
英文摘要: An efficient regioselective fluorotrifluoro-methylation of unactivated alkenes has been developed. The reaction of alkenes with (trifluoromethyl) trimethylsilane (TMSCF3) and Selectfluor in the presence of silver trifluoromethanesulfonate (AgOTf), cesium fluoride (CsF), and iodobenzene diacetate [PhI(OAc)(2)] in N,N-dimethylformamide (DMF) at -20 degrees C gave the corresponding fluorotrifluoromethylated products in moderate to good yields. The silver salt turns out to be crucial for this transformation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000356373200008
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39728
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.东华大学

Recommended Citation:
Yu W,Xu XH,Qing FL. Silver-Mediated Oxidative Fluorotrifluoromethylation of Unactivated Alkenes[J]. Adv. Synth. Catal.,2015,357(9):2039-2044.
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