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学科主题: 氟化学
题名: Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts
其他题名: Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts
作者: Wu J(吴江); Gu Y(古阳); Leng XB(冷雪冰); Shen QL(沈其龙)
通讯作者: 沈其龙
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201502113
卷: 54, 期:26, 页:7648-7652
收录类别: SCI
文章类型: 论文
英文摘要: An efficient copper-promoted difluoromethylthiolation of aryl and heteroaryl diazonium salts is described. The reaction is conducted under mild reaction conditions and various functional groups were compatible. In addition, reactions of heteroaryl diazonium salts such as pyridyl, quinolinyl, benzothiazolyl, thiophenyl, carbazolyl, and pyrazolyl diazonium salts occurred smoothly to afford the medicinally important difluoromethylthiolated heteroarenes. Furthermore, a more practical one-pot direct diazotization and difluoromethylthiolation protocol was developed, and it converts the aniline derivatives into difluoromethylthiolated arenes. The utility of the method is demonstrated by difluoromethylthiolation of a number of natural products and drug molecules.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000356390900035
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39727
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Wu J,Gu Y,Leng XB,et al. Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts[J]. Angew. Chem.-Int. Edit.,2015,54(26):7648-7652.
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