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Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts
其他题名Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts
Wu J(吴江); Gu Y(古阳); Leng XB(冷雪冰); Shen QL(沈其龙)
2015
发表期刊Angew. Chem.-Int. Edit.
卷号54期号:26页码:7648-7652
摘要An efficient copper-promoted difluoromethylthiolation of aryl and heteroaryl diazonium salts is described. The reaction is conducted under mild reaction conditions and various functional groups were compatible. In addition, reactions of heteroaryl diazonium salts such as pyridyl, quinolinyl, benzothiazolyl, thiophenyl, carbazolyl, and pyrazolyl diazonium salts occurred smoothly to afford the medicinally important difluoromethylthiolated heteroarenes. Furthermore, a more practical one-pot direct diazotization and difluoromethylthiolation protocol was developed, and it converts the aniline derivatives into difluoromethylthiolated arenes. The utility of the method is demonstrated by difluoromethylthiolation of a number of natural products and drug molecules.
文章类型论文
学科领域氟化学
DOI10.1002/anie.201502113
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000356390900035
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文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39727
专题中科院有机氟化学重点实验室
通讯作者Shen QL(沈其龙)
作者单位中科院上海有机化学研究所, 有机氟化学重点实验室
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GB/T 7714
Wu J,Gu Y,Leng XB,et al. Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts[J]. Angew. Chem.-Int. Edit.,2015,54(26):7648-7652.
APA 吴江,古阳,冷雪冰,&沈其龙.(2015).Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts.Angew. Chem.-Int. Edit.,54(26),7648-7652.
MLA 吴江,et al."Copper-Promoted Sandmeyer Difluoromethylthiolation of Aryl and Heteroaryl Diazonium Salts".Angew. Chem.-Int. Edit. 54.26(2015):7648-7652.
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