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学科主题: 氟化学
题名: Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides
其他题名: 杂芳基亚砜对双芳基酮的羰基烯化反应
作者: Gao B(高兵); Hu JY(胡靖宇); Zhao YC(赵延川); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Tetrahedron Lett.
发表日期: 2015
DOI: 10.1016/j.tetlet.2015.05.034
卷: 56, 期:28, 页:4180-4183
收录类别: SCI
文章类型: 论文
英文摘要: Heteroaryl sulfones are capable of converting the carbonyl functionalities to alkenyl motifs, which is well-known as Julia-Kocienski olefination reaction. However, their sulfoxide analogues have failed in such an olefination reaction for over twenty years. In this Letter, we demonstrate that the heteroaryl sulfoxide-participated carbonyl olefination reaction can be realized under certain conditions. Furthermore, a novel defluorinative olefination of diaryl ketones has been achieved with 2-pyridyl sulfoxides. (C) 2015 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000356757200007
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39726
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Gao B,Hu JY,Zhao YC,et al. Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides[J]. Tetrahedron Lett.,2015,56(28):4180-4183.
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