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Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides
Alternative Title杂芳基亚砜对双芳基酮的羰基烯化反应
Gao B(高兵); Hu JY(胡靖宇); Zhao YC(赵延川); Hu JB(胡金波)
Source PublicationTetrahedron Lett.
AbstractHeteroaryl sulfones are capable of converting the carbonyl functionalities to alkenyl motifs, which is well-known as Julia-Kocienski olefination reaction. However, their sulfoxide analogues have failed in such an olefination reaction for over twenty years. In this Letter, we demonstrate that the heteroaryl sulfoxide-participated carbonyl olefination reaction can be realized under certain conditions. Furthermore, a novel defluorinative olefination of diaryl ketones has been achieved with 2-pyridyl sulfoxides. (C) 2015 Elsevier Ltd. All rights reserved.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000356757200007
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Document Type期刊论文
Corresponding AuthorHu JB(胡金波)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Gao B,Hu JY,Zhao YC,et al. Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides[J]. Tetrahedron Lett.,2015,56(28):4180-4183.
APA 高兵,胡靖宇,赵延川,&胡金波.(2015).Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides.Tetrahedron Lett.,56(28),4180-4183.
MLA 高兵,et al."Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides".Tetrahedron Lett. 56.28(2015):4180-4183.
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