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学科主题: 氟化学
题名: Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation
其他题名: 脱羧所产生二氟卡宾的二氟甲基化及二氟环丙烯化
作者: Deng XY(邓晓云); Lin JH(林锦鸿); Zheng J(郑剑); Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Chem. Commun.
发表日期: 2015
DOI: 10.1039/c5cc02736e
卷: 51, 期:42, 页:8805-8808
收录类别: SCI
文章类型: 论文
英文摘要: Difluoromethylation of the activated X-H bond (X = N, O and S) and aliphatic thiols, and gem-difluorocyclopropenation of alkynes with difluorocarbene generated in situ from difluoromethylene phosphobetaine (Ph3P+CF2CO2-) by decarboxylation occurred smoothly without the presence of any base or other additives.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000354477600018
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39725
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Deng XY,Lin JH,Zheng J,et al. Difluoromethylation and gem-difluorocyclopropenation with difluorocarbene generated by decarboxylation[J]. Chem. Commun.,2015,51(42):8805-8808.
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