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Synthesis of Chiral beta-Aminomalonates from 2-Chlorotetrafluoroethanesulfinyl Aldimines through the Mannich Reaction
Alternative Title通过Mannich反应由2-氯四氟乙基亚磺酰醛亚胺合成手性β-胺基丙二酸酯
Yang K(杨凯); Jiang M(蒋敏); Liu JT(刘金涛)
2015
Source PublicationEur. J. Org. Chem.
Issue14Pages:3109-3115
AbstractAn efficient method for the synthesis of chiral beta-aminomalonates in good yields and with high diastereoselectivities was achieved through Mannich reactions between 2-chlorotetrafluoroethanesulfinyl aldimines and dialkyl malonates in the presence of N-trimethylsilylimidazole. Further transformation of the products gave the corresponding beta-lactams in good yields and with high optical purities.
Subtype论文
Subject Area氟化学
DOI10.1002/ejoc.201500134
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000354212000018
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39722
Collection中科院有机氟化学重点实验室
Corresponding AuthorLiu JT(刘金涛)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Yang K,Jiang M,Liu JT. Synthesis of Chiral beta-Aminomalonates from 2-Chlorotetrafluoroethanesulfinyl Aldimines through the Mannich Reaction[J]. Eur. J. Org. Chem.,2015(14):3109-3115.
APA 杨凯,蒋敏,&刘金涛.(2015).Synthesis of Chiral beta-Aminomalonates from 2-Chlorotetrafluoroethanesulfinyl Aldimines through the Mannich Reaction.Eur. J. Org. Chem.(14),3109-3115.
MLA 杨凯,et al."Synthesis of Chiral beta-Aminomalonates from 2-Chlorotetrafluoroethanesulfinyl Aldimines through the Mannich Reaction".Eur. J. Org. Chem. .14(2015):3109-3115.
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