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学科主题: 氟化学
题名: Synthesis of Chiral beta-Aminomalonates from 2-Chlorotetrafluoroethanesulfinyl Aldimines through the Mannich Reaction
其他题名: 通过Mannich反应由2-氯四氟乙基亚磺酰醛亚胺合成手性β-胺基丙二酸酯
作者: Yang K(杨凯); Jiang M(蒋敏); Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Eur. J. Org. Chem.
发表日期: 2015
DOI: 10.1002/ejoc.201500134
期: 14, 页:3109-3115
收录类别: SCI
文章类型: 论文
英文摘要: An efficient method for the synthesis of chiral beta-aminomalonates in good yields and with high diastereoselectivities was achieved through Mannich reactions between 2-chlorotetrafluoroethanesulfinyl aldimines and dialkyl malonates in the presence of N-trimethylsilylimidazole. Further transformation of the products gave the corresponding beta-lactams in good yields and with high optical purities.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000354212000018
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39722
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Yang K,Jiang M,Liu JT. Synthesis of Chiral beta-Aminomalonates from 2-Chlorotetrafluoroethanesulfinyl Aldimines through the Mannich Reaction[J]. Eur. J. Org. Chem.,2015(14):3109-3115.
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