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学科主题: 氟化学
题名: Copper-Mediated Radical 1,2-Bis(trifluoromethylation) of Alkenes with Sodium Trifluoromethanesulfinate
其他题名: 铜参与烯烃与三氟甲基亚磺酸钠的自由基1,2-双三氟甲基化反应
作者: Yang B(杨斌)1; Xu XH(徐修华)1; Qing FL(卿凤翎)1
通讯作者: 卿凤翎
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/acs.orglett.5b00601
卷: 17, 期:8, 页:1906-1909
收录类别: SCI
文章类型: 论文
英文摘要: An efficient chemoselective 1,2-bis(trifluoromethylation) of alkenes with CF3SO2Na promoted by t-BuOOH/CuCl was developed. This protocol provided the first convenient preparation of 1,2-bis(trifluoromethylated) compounds by the vicinal difunctionalization of alkenes. The chemoselectivity of this reaction was accomplished by increasing the concentration of the CF3 radical.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000353314800023
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39719
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.东华大学

Recommended Citation:
Yang B,Xu XH,Qing FL. Copper-Mediated Radical 1,2-Bis(trifluoromethylation) of Alkenes with Sodium Trifluoromethanesulfinate[J]. Org. Lett.,2015,17(8):1906-1909.
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