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学科主题: 氟化学
题名: Fluoroalkylative Aryl Migration of Conjugated N-Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates
其他题名: 用易得的二氟和一氟烷基亚磺酸钠试剂对共轭N-芳基磺酰胺的氟烷基化-芳基迁移反应
作者: He ZB(何正标); Tan P(谭平); Ni CF(倪传法); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/acs.orglett.5b00308
卷: 17, 期:8, 页:1838-1841
收录类别: SCI
文章类型: 论文
英文摘要: Fluorinated sulfinate salts RfSO2Na (R-f = CF2H, CF2Ph, and CH2F) have been prepared via NaBH4-mediated reduction of the corresponding benzo[d]thiazol-2-yl sulfones, and their synthetic application as di- and monofluoroalkyl radical precursors is demonstrated in the silver-catalyzed cascade fluoroalkylation/aryl migration/SO2 extrusion of conjugated N-arylsulfonylated amides.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000353314800006
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39718
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
He ZB,Tan P,Ni CF,et al. Fluoroalkylative Aryl Migration of Conjugated N-Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates[J]. Org. Lett.,2015,17(8):1838-1841.
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