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学科主题: 氟化学
题名: Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent
其他题名: 结构活性相关-三氟甲基次磺酸酯: 新型亲电三氟甲硫基化试剂的研制
作者: Shao XX(邵欣欣); Xu CF(徐春发); Lv L(吕龙); Shen QL(沈其龙)
通讯作者: 吕龙 ; 沈其龙
刊名: J. Org. Chem.
发表日期: 2015
DOI: 10.1021/jo502645m
卷: 80, 期:6, 页:3012-3021
收录类别: SCI
文章类型: 论文
英文摘要: A family of electrophilic trifluoromethanesulfenates was prepared. Structure-reactivity relationship studies showed that the substituted groups on the aryl ring of the trifluoromethylthiolating reagent did not have an obvious influence on their reactivities. A simplified electrophilic trifluoromethylthiolating reagent 1c was then identified that can react with a wide range of nucleophiles such as Grignard reagents, arylboronic acids, alkynes, indoles, beta-ketoesters, oxindoles, and sodium sulfinates under mild reaction conditions. A variety of functional groups were tolerated under these conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000351558400006
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39716
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Shao XX,Xu CF,Lv L,et al. Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent[J]. J. Org. Chem.,2015,80(6):3012-3021.
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