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Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent
Alternative Title结构活性相关-三氟甲基次磺酸酯: 新型亲电三氟甲硫基化试剂的研制
Shao XX(邵欣欣); Xu CF(徐春发); Lv L(吕龙); Shen QL(沈其龙)
2015
Source PublicationJ. Org. Chem.
Volume80Issue:6Pages:3012-3021
AbstractA family of electrophilic trifluoromethanesulfenates was prepared. Structure-reactivity relationship studies showed that the substituted groups on the aryl ring of the trifluoromethylthiolating reagent did not have an obvious influence on their reactivities. A simplified electrophilic trifluoromethylthiolating reagent 1c was then identified that can react with a wide range of nucleophiles such as Grignard reagents, arylboronic acids, alkynes, indoles, beta-ketoesters, oxindoles, and sodium sulfinates under mild reaction conditions. A variety of functional groups were tolerated under these conditions.
Subtype论文
Subject Area氟化学
DOI10.1021/jo502645m
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000351558400006
Citation statistics
Cited Times:81[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39716
Collection中科院有机氟化学重点实验室
Corresponding AuthorLv L(吕龙); Shen QL(沈其龙)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Shao XX,Xu CF,Lv L,et al. Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent[J]. J. Org. Chem.,2015,80(6):3012-3021.
APA 邵欣欣,徐春发,吕龙,&沈其龙.(2015).Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent.J. Org. Chem.,80(6),3012-3021.
MLA 邵欣欣,et al."Structure-Reactivity Relationship of Trifluoromethanesulfenates: Discovery of an Electrophilic Trifluoromethylthiolating Reagent".J. Org. Chem. 80.6(2015):3012-3021.
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