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学科主题: 氟化学
题名: Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes
其他题名: 铁促进的未活化烯烃马氏选择性的氢三氟甲硫基反应
作者: Yang T(杨涛); Lv L(吕龙); Shen QL(沈其龙)
通讯作者: 吕龙 ; 沈其龙
刊名: Chem. Commun.
发表日期: 2015
DOI: 10.1039/c4cc08655d
卷: 51, 期:25, 页:5479-5481
收录类别: SCI
文章类型: 论文
英文摘要: An iron-mediated hydro-trifluoromethylthiolation of unactivated olefins under mild conditions was described for the first time. The reaction occurred to full conversion within 30 min at 0 degrees C and tolerates a variety of functional groups. Preliminary mechanistic studies suggested that the reaction proceeds via a free-radical pathway.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000351393600069
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39715
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Yang T,Lv L,Shen QL. Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes[J]. Chem. Commun.,2015,51(25):5479-5481.
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