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过渡金属促进的二氟烷基化和一氟烷基化反应研究进展
Alternative TitleAdvances in Transition-Metal-Mediated Di- and Monofluoroalkylations
倪传法; 朱林桂; 胡金波
2015
Source Publication化学学报
Volume73Issue:2Pages:90-115
Other AbstractTransition-metal-mediated fluoroalicylation is a hot research topic in current organofluorine chemistry. In the past five years, due to the development of new perfluoroallcylation reagents and methodologies, significant progress has been made in the field of transition-metal-mediated perfluoroalkylation. Compared with perfluoroallcylation, di- and monofluoroalkylation can not only introduce fluorine atom(s) into a molecule, but also install a non-fluorinated moiety simultaneously; therefore, in organic synthesis, these reactions are of higher step economy than the direct fluorination reactions. Although analogous to transition-metal-mediated perfluoroallcylations, the di- and monofluoroallcylation have been relatively less developed; therefore, there are still many opportunities for their development. In this review, we have made a survey on transition-metal-mediated di- and monofluoroalkylation reactions that were published in the past nearly 30 years. To our knowledge, this is the first rather comprehensive review on this topic. This review is divided into five sections. The first section is the general introduction on di- and monofluoroalkylation. The second and third sections focus on the historical development of transition-metal-mediated di- and monofluoroallcylation with reagents that contain functional groups. These two sections are subdivided according to the reactions types, that is, fluoroalkylation of unsaturated organohalides, fluoroalkylation of the carbon-hydrogen bonds of unsaturated systems (arenes, alkenes, alkynes, and carbonyl compounds), fluoroalkylation of organoborane reagents and organometallic reagents, fluoroallcyl addition to unsaturated carbon-carbon bonds. The fourth section puts an emphasis on the transition-metal-promoted di- and monofluoromethylation reactions. The final section gives some perspectives on the future development of this chemistry.
Subtype论文
Subject Area氟化学
DOI10.6023/A14110758
URL查看原文
Indexed BySCI
Language中文
WOS IDWOS:000351421800002
Citation statistics
Cited Times:93[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39714
Collection中科院有机氟化学重点实验室
Corresponding Author胡金波
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
倪传法,朱林桂,胡金波. 过渡金属促进的二氟烷基化和一氟烷基化反应研究进展[J]. 化学学报,2015,73(2):90-115.
APA 倪传法,朱林桂,&胡金波.(2015).过渡金属促进的二氟烷基化和一氟烷基化反应研究进展.化学学报,73(2),90-115.
MLA 倪传法,et al."过渡金属促进的二氟烷基化和一氟烷基化反应研究进展".化学学报 73.2(2015):90-115.
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