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过渡金属促进的二氟烷基化和一氟烷基化反应研究进展
其他题名Advances in Transition-Metal-Mediated Di- and Monofluoroalkylations
倪传法; 朱林桂; 胡金波
2015
发表期刊化学学报
卷号73期号:2页码:90-115
其他摘要Transition-metal-mediated fluoroalicylation is a hot research topic in current organofluorine chemistry. In the past five years, due to the development of new perfluoroallcylation reagents and methodologies, significant progress has been made in the field of transition-metal-mediated perfluoroalkylation. Compared with perfluoroallcylation, di- and monofluoroalkylation can not only introduce fluorine atom(s) into a molecule, but also install a non-fluorinated moiety simultaneously; therefore, in organic synthesis, these reactions are of higher step economy than the direct fluorination reactions. Although analogous to transition-metal-mediated perfluoroallcylations, the di- and monofluoroallcylation have been relatively less developed; therefore, there are still many opportunities for their development. In this review, we have made a survey on transition-metal-mediated di- and monofluoroalkylation reactions that were published in the past nearly 30 years. To our knowledge, this is the first rather comprehensive review on this topic. This review is divided into five sections. The first section is the general introduction on di- and monofluoroalkylation. The second and third sections focus on the historical development of transition-metal-mediated di- and monofluoroallcylation with reagents that contain functional groups. These two sections are subdivided according to the reactions types, that is, fluoroalkylation of unsaturated organohalides, fluoroalkylation of the carbon-hydrogen bonds of unsaturated systems (arenes, alkenes, alkynes, and carbonyl compounds), fluoroalkylation of organoborane reagents and organometallic reagents, fluoroallcyl addition to unsaturated carbon-carbon bonds. The fourth section puts an emphasis on the transition-metal-promoted di- and monofluoromethylation reactions. The final section gives some perspectives on the future development of this chemistry.
文章类型论文
学科领域氟化学
DOI10.6023/A14110758
URL查看原文
收录类别SCI
语种中文
WOS记录号WOS:000351421800002
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被引频次:85[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39714
专题中科院有机氟化学重点实验室
通讯作者胡金波
作者单位中科院上海有机化学研究所, 有机氟化学重点实验室
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倪传法,朱林桂,胡金波. 过渡金属促进的二氟烷基化和一氟烷基化反应研究进展[J]. 化学学报,2015,73(2):90-115.
APA 倪传法,朱林桂,&胡金波.(2015).过渡金属促进的二氟烷基化和一氟烷基化反应研究进展.化学学报,73(2),90-115.
MLA 倪传法,et al."过渡金属促进的二氟烷基化和一氟烷基化反应研究进展".化学学报 73.2(2015):90-115.
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