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学科主题: 氟化学
题名: 过渡金属促进的二氟烷基化和一氟烷基化反应研究进展
其他题名: Advances in Transition-Metal-Mediated Di- and Monofluoroalkylations
作者: 倪传法; 朱林桂; 胡金波
通讯作者: 胡金波
刊名: 化学学报
发表日期: 2015
DOI: 10.6023/A14110758
卷: 73, 期:2, 页:90-115
收录类别: SCI
文章类型: 论文
英文摘要: Transition-metal-mediated fluoroalicylation is a hot research topic in current organofluorine chemistry. In the past five years, due to the development of new perfluoroallcylation reagents and methodologies, significant progress has been made in the field of transition-metal-mediated perfluoroalkylation. Compared with perfluoroallcylation, di- and monofluoroalkylation can not only introduce fluorine atom(s) into a molecule, but also install a non-fluorinated moiety simultaneously; therefore, in organic synthesis, these reactions are of higher step economy than the direct fluorination reactions. Although analogous to transition-metal-mediated perfluoroallcylations, the di- and monofluoroallcylation have been relatively less developed; therefore, there are still many opportunities for their development. In this review, we have made a survey on transition-metal-mediated di- and monofluoroalkylation reactions that were published in the past nearly 30 years. To our knowledge, this is the first rather comprehensive review on this topic. This review is divided into five sections. The first section is the general introduction on di- and monofluoroalkylation. The second and third sections focus on the historical development of transition-metal-mediated di- and monofluoroallcylation with reagents that contain functional groups. These two sections are subdivided according to the reactions types, that is, fluoroalkylation of unsaturated organohalides, fluoroalkylation of the carbon-hydrogen bonds of unsaturated systems (arenes, alkenes, alkynes, and carbonyl compounds), fluoroalkylation of organoborane reagents and organometallic reagents, fluoroallcyl addition to unsaturated carbon-carbon bonds. The fourth section puts an emphasis on the transition-metal-promoted di- and monofluoromethylation reactions. The final section gives some perspectives on the future development of this chemistry.
语种: 中文
相关网址: 查看原文
WOS记录号: WOS:000351421800002
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39714
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
倪传法,朱林桂,胡金波. 过渡金属促进的二氟烷基化和一氟烷基化反应研究进展[J]. 化学学报,2015,73(2):90-115.
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