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Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species
Alternative Title单质铜调控下2-溴-1,1,2,2-四氟乙基化合物对碘苯的氟烷基化反应: R取代基对RCF2Cu物种的反应性影响研究
Zhu JM(朱杰明); Ni CF(倪传法); Gao B(高兵); Hu JB(胡金波)
2015
Source PublicationJ. Fluor. Chem.
Volume171Pages:139-147
AbstractWe have made a systematic investigation on the copper(0)-mediated tetrafluoroethylenation of iodobenzene with structurally diverse 2-bromo-1,1,2,2-tetrafluoroethyl compounds. A comparison of this reaction with 1,2,2-trifluoro-1-phenylethylation and the known functionalized difluoroalkylation demonstrates that the substituent R of alpha,alpha-difluoroalkyl copper species RCF2Cu plays a crucial role on their reactivity, which is believed to be useful for the development of new fluoroalkylation reactions under the promotion of transition metals. (C) 2014 Elsevier B.V. All rights reserved.
Subtype论文
Subject Area氟化学
DOI10.1016/j.jfluchem.2014.08.011
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000350943600022
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39713
Collection中科院有机氟化学重点实验室
Corresponding AuthorHu JB(胡金波)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Zhu JM,Ni CF,Gao B,et al. Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species[J]. J. Fluor. Chem.,2015,171:139-147.
APA 朱杰明,倪传法,高兵,&胡金波.(2015).Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species.J. Fluor. Chem.,171,139-147.
MLA 朱杰明,et al."Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species".J. Fluor. Chem. 171(2015):139-147.
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