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学科主题: 氟化学
题名: Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species
其他题名: 单质铜调控下2-溴-1,1,2,2-四氟乙基化合物对碘苯的氟烷基化反应: R取代基对RCF2Cu物种的反应性影响研究
作者: Zhu JM(朱杰明); Ni CF(倪传法); Gao B(高兵); Hu JB(胡金波)
通讯作者: 胡金波
刊名: J. Fluor. Chem.
发表日期: 2015
DOI: 10.1016/j.jfluchem.2014.08.011
卷: 171, 页:139-147
收录类别: SCI
文章类型: 论文
英文摘要: We have made a systematic investigation on the copper(0)-mediated tetrafluoroethylenation of iodobenzene with structurally diverse 2-bromo-1,1,2,2-tetrafluoroethyl compounds. A comparison of this reaction with 1,2,2-trifluoro-1-phenylethylation and the known functionalized difluoroalkylation demonstrates that the substituent R of alpha,alpha-difluoroalkyl copper species RCF2Cu plays a crucial role on their reactivity, which is believed to be useful for the development of new fluoroalkylation reactions under the promotion of transition metals. (C) 2014 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000350943600022
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39713
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Zhu JM,Ni CF,Gao B,et al. Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species[J]. J. Fluor. Chem.,2015,171:139-147.
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