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学科主题: 氟化学
题名: Direct Trifluoromethylthiolation of Unactivated C(sp(3))-H Using Silver(I) Trifluoromethanethiolate and Potassium Persulfate
其他题名: 使用三氟甲硫基银和过硫酸钾的不饱和C(sp3)-H的三氟甲硫基化反应
作者: Wu H(吴浩)1; Xiao ZW(肖智伟)1; Wu JH(吴俊辉)1; Guo Y(郭勇)1; Xiao JC(肖吉昌)1; Liu C(刘超)1; Chen QY(陈庆云)1
通讯作者: 刘超 ; 陈庆云
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201411953
卷: 54, 期:13, 页:4070-4074
收录类别: SCI
文章类型: 论文
英文摘要: A practical and efficient method for the direct trifluoromethylthiolation of unactivated C(sp3)-H bonds by AgSCF3/K2S2O8 under mild conditions is described. The reaction has a good functional-group tolerance and good selectivity. Initial mechanistic investigations indicate that the reaction may involve a radical process in which K2S2O8 plays key roles in both the activation of the C(sp3)-H bond and the oxidation of AgSCF3.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000351204600041
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39710
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.上海应用技术学院

Recommended Citation:
Wu H,Xiao ZW,Wu JH,et al. Direct Trifluoromethylthiolation of Unactivated C(sp(3))-H Using Silver(I) Trifluoromethanethiolate and Potassium Persulfate[J]. Angew. Chem.-Int. Edit.,2015,54(13):4070-4074.
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