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1,2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells
Alternative Title1,2-二甲基咪唑盐功能化的交联碱性阴离子交换膜用于碱性直接甲醇燃料电池
Yang CR(杨丛荣)1; Wang SL(王素力)1; Jiang LH(姜鲁华)1; Hu JB(胡金波)1; Ma WJ(马文佳)1; Sun GQ(孙公权)1
2015
Source PublicationInt. J. Hydrog. Energy
Volume40Issue:5Pages:2363-2370
AbstractThe cross-linked and alkali stable alkaline anion exchange membranes (AAEMs) based on 1,2-dimethylimidazolium (proved to be much more stable than C2-unsubstituted imidazolium cation) were prepared by a hot-pressing method. The properties of these membranes, e.g., water uptake, swelling degree, ion-exchange capacity, conductivity and thermal and chemical stability, were characterized systematically. The swelling degree of the membranes decreases with the decrease of the amount of 1,2-dimethylimidazolium salt, up to 5.8%. The membranes are thermally stable below 200 degrees C. Alkaline direct methanol fuel cell (ADMFC) fabricated by using CoOx/C as the cathode catalyst and PtRu/C as the anode catalyst presents a promising performance with the peak power density of 12.7 mW cm(-2) at a current density of 45 mA cm(-2), indicating that the 1,2-dimethylimidazolium-functionalized AAEMs are promising for the application in ADMFCs. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
Subtype论文
Subject Area有机化学
DOI10.1016/j.ijhydene.2014.12.050
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000349579200031
Citation statistics
Cited Times:23[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39709
Collection中科院有机氟化学重点实验室
Corresponding AuthorSun GQ(孙公权)
Affiliation1.中科院大连化学物理研究所
2.中国科学院大学
3.中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Yang CR,Wang SL,Jiang LH,et al. 1,2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells[J]. Int. J. Hydrog. Energy,2015,40(5):2363-2370.
APA 杨丛荣,王素力,姜鲁华,胡金波,马文佳,&孙公权.(2015).1,2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells.Int. J. Hydrog. Energy,40(5),2363-2370.
MLA 杨丛荣,et al."1,2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells".Int. J. Hydrog. Energy 40.5(2015):2363-2370.
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