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Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide
Alternative Title醇与银三氟甲硫基银和四正丁基碘化铵的直接三氟甲硫基化
Liu JB(刘建波)1; Xu XH(徐修华)1; Chen ZH(陈增浩)1; Qing FL(卿凤翎)1
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:3Pages:897-900
AbstractAn unprecedented reaction for the direct trifluoromethylthiolation and fluorination of alkyl alcohols using AgSCF3 and nBu(4)NI has been developed. The trifluoromethylthiolated compounds and alkyl fluorides were selectively formed by changing the ratio of AgSCF3/nBu(4)NI. This protocol is tolerant of different functional groups and might be applicable to late-stage trifluoromethylthiolation of alcohols.
Subtype论文
Subject Area氟化学
DOI10.1002/anie.201409983
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000348372200028
Citation statistics
Cited Times:94[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39708
Collection中科院有机氟化学重点实验室
Corresponding AuthorQing FL(卿凤翎)
Affiliation1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.东华大学
Recommended Citation
GB/T 7714
Liu JB,Xu XH,Chen ZH,et al. Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide[J]. Angew. Chem.-Int. Edit.,2015,54(3):897-900.
APA 刘建波,徐修华,陈增浩,&卿凤翎.(2015).Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide.Angew. Chem.-Int. Edit.,54(3),897-900.
MLA 刘建波,et al."Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide".Angew. Chem.-Int. Edit. 54.3(2015):897-900.
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