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学科主题: 氟化学
题名: Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide
其他题名: 醇与银三氟甲硫基银和四正丁基碘化铵的直接三氟甲硫基化
作者: Liu JB(刘建波)1; Xu XH(徐修华)1; Chen ZH(陈增浩)1; Qing FL(卿凤翎)1
通讯作者: 卿凤翎
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201409983
卷: 54, 期:3, 页:897-900
收录类别: SCI
文章类型: 论文
英文摘要: An unprecedented reaction for the direct trifluoromethylthiolation and fluorination of alkyl alcohols using AgSCF3 and nBu(4)NI has been developed. The trifluoromethylthiolated compounds and alkyl fluorides were selectively formed by changing the ratio of AgSCF3/nBu(4)NI. This protocol is tolerant of different functional groups and might be applicable to late-stage trifluoromethylthiolation of alcohols.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000348372200028
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39708
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 有机氟化学重点实验室
2.东华大学

Recommended Citation:
Liu JB,Xu XH,Chen ZH,et al. Direct Dehydroxytrifluoromethylthiolation of Alcohols Using Silver(I) Trifluoromethanethiolate and Tetra-n-butylammonium Iodide[J]. Angew. Chem.-Int. Edit.,2015,54(3):897-900.
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