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Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide
Alternative Title铜调控下用三氟甲基苯基砜进行的三氟甲基化
Li XJ(李新进)1; Zhao JW(赵经纬)1; Zhang L(张梁)1; Hu MY(胡明友)1; Wang LM(王利民)1; Hu JB(胡金波)1
Source PublicationOrg. Lett.
AbstractA new method for the generation of trifluoromethylcopper ("CuCF3") species from readily available phenyl trifluoromethyl sulfoxide has been developed. The "CuCF3" reagent can be applied in efficient trifluoromethylations of aryl iodides and activated aryl bromides in the absence of additional ligands. Furthermore, the "CuCF3" species can also undergo oxidative cross-coupling with terminal alkynes and arylboronic acids.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000348331800033
Citation statistics
Cited Times:37[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorWang LM(王利民); Hu JB(胡金波)
2.中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Li XJ,Zhao JW,Zhang L,et al. Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide[J]. Org. Lett.,2015,17(2):298-301.
APA 李新进,赵经纬,张梁,胡明友,王利民,&胡金波.(2015).Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide.Org. Lett.,17(2),298-301.
MLA 李新进,et al."Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide".Org. Lett. 17.2(2015):298-301.
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