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学科主题: 氟化学
题名: Metal-Mediated Reformatsky Reaction of Bromodifluoromethyl Ketone and Imine
其他题名: 金属促进的溴二氟甲基酮和亚胺的Reformatsky反应
作者: Cao CR(曹春如); Jiang M(蒋敏); Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: Eur. J. Org. Chem.
发表日期: 2015
DOI: 10.1002/ejoc.201403424
期: 5, 页:1144-1151
收录类别: SCI
文章类型: 论文
英文摘要: The Reformatsky reaction of bromodifluoromethyl ketones and imines took place readily in the presence of Zn/CuCl at room temperature to afford beta-amino alpha,alpha-difluoro ketones in good yields. Using (S)-tert-butanesulfinyl as a chiral auxiliary, the asymmetric Reformatsky reaction was also achieved and found to proceed with excellent diastereoselectivities. A plausible model is proposed to account for the high stereoselectivity of the reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000349391700028
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39704
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Cao CR,Jiang M,Liu JT. Metal-Mediated Reformatsky Reaction of Bromodifluoromethyl Ketone and Imine[J]. Eur. J. Org. Chem.,2015(5):1144-1151.
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