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学科主题: 氟化学
题名: 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation
其他题名: DBU促进下二氟卡宾的分解及三氟甲基化
作者: Zheng J(郑剑); Lin JH(林锦鸿); Deng XY(邓晓云); Xiao JC(肖吉昌)
通讯作者: 肖吉昌
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/ol503548s
卷: 17, 期:3, 页:532-535
收录类别: SCI
文章类型: 论文
英文摘要: Difluorocarbene derived from various carbene precursors could be effectively decomposed by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). This decomposition process was successfully applied in the subsequent trifluoromethylation of a variety of (hetero)aryl iodides without the addition of an external fluoride ion. Mechanistic investigation revealed the detailed difluorocarbene conversion process in which the decomposed difluorocarbene is finally transformed into a fluoride ion and carbon monoxide.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000349274200036
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39703
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Zheng J,Lin JH,Deng XY,et al. 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation[J]. Org. Lett.,2015,17(3):532-535.
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