SIOC OpenIR  > 中科院有机氟化学重点实验室
1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation
Alternative TitleDBU促进下二氟卡宾的分解及三氟甲基化
Zheng J(郑剑); Lin JH(林锦鸿); Deng XY(邓晓云); Xiao JC(肖吉昌)
Source PublicationOrg. Lett.
AbstractDifluorocarbene derived from various carbene precursors could be effectively decomposed by 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU). This decomposition process was successfully applied in the subsequent trifluoromethylation of a variety of (hetero)aryl iodides without the addition of an external fluoride ion. Mechanistic investigation revealed the detailed difluorocarbene conversion process in which the decomposed difluorocarbene is finally transformed into a fluoride ion and carbon monoxide.
Subject Area氟化学
Indexed BySCI
WOS IDWOS:000349274200036
Citation statistics
Cited Times:40[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorXiao JC(肖吉昌)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Zheng J,Lin JH,Deng XY,et al. 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation[J]. Org. Lett.,2015,17(3):532-535.
APA 郑剑,林锦鸿,邓晓云,&肖吉昌.(2015).1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation.Org. Lett.,17(3),532-535.
MLA 郑剑,et al."1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU)-Promoted Decomposition of Difluorocarbene and the Subsequent Trifluoromethylation".Org. Lett. 17.3(2015):532-535.
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