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Insight into "entrainment" in S(RN)1 reactions of 2,2-dichloro-1,1, 1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4
Alternative TitleInsight into "entrainment" in S(RN)1 reactions of 2,2-dichloro-1,1, 1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4
Tang XJ(唐小军); Chen QY(陈庆云)
2015
Source PublicationJ. Fluor. Chem.
Volume169Pages:1-5
AbstractAn interesting entrainment process in S(RN)1 reactions of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with thiolates were studied by experiments and DFT calculations. The radical-anion intermediate, generated from coupling of the fluorinated radical with the thiolate was considered as the key intermediate in this reaction. (C) 2014 Elsevier B.V. All rights reserved.
Subtype论文
Subject Area氟化学
DOI10.1016/j.jfluchem.2014.10.006
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000348087000001
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39701
Collection中科院有机氟化学重点实验室
Corresponding AuthorChen QY(陈庆云)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Tang XJ,Chen QY. Insight into "entrainment" in S(RN)1 reactions of 2,2-dichloro-1,1, 1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4[J]. J. Fluor. Chem.,2015,169:1-5.
APA 唐小军,&陈庆云.(2015).Insight into "entrainment" in S(RN)1 reactions of 2,2-dichloro-1,1, 1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4.J. Fluor. Chem.,169,1-5.
MLA 唐小军,et al."Insight into "entrainment" in S(RN)1 reactions of 2,2-dichloro-1,1, 1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4".J. Fluor. Chem. 169(2015):1-5.
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