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学科主题: 氟化学
题名: Insight into "entrainment" in S(RN)1 reactions of 2,2-dichloro-1,1, 1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4
其他题名: Insight into "entrainment" in S(RN)1 reactions of 2,2-dichloro-1,1, 1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4
作者: Tang XJ(唐小军); Chen QY(陈庆云)
通讯作者: 陈庆云
刊名: J. Fluor. Chem.
发表日期: 2015
DOI: 10.1016/j.jfluchem.2014.10.006
卷: 169, 页:1-5
收录类别: SCI
文章类型: 论文
英文摘要: An interesting entrainment process in S(RN)1 reactions of 2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) with thiolates were studied by experiments and DFT calculations. The radical-anion intermediate, generated from coupling of the fluorinated radical with the thiolate was considered as the key intermediate in this reaction. (C) 2014 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000348087000001
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39701
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Tang XJ,Chen QY. Insight into "entrainment" in S(RN)1 reactions of 2,2-dichloro-1,1, 1-trifluoroethane(HCFC-123) with thiolates initiated by Na2S2O4[J]. J. Fluor. Chem.,2015,169:1-5.
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