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AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones
Alternative Title氟化银促进的双烯烃氟化交叉偶联反应: 一种便捷合成α-三氟甲基烯烃和 β-三氟甲基酮的方法
Gao B(高兵); Zhao YC(赵延川); Hu JB(胡金波)
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:2Pages:638-642
AbstractA AgF-mediated fluorination with a concomitant cross-coupling between a gem-difluoroolefin and a non-fluorinated olefin is reported. This highly efficient method provides facile access to both -CF3 alkenes and -CF3 ketones, which otherwise remain challenging to be directly prepared. The application of this method is further demonstrated by the synthesis of bioactive isoxazoline derivatives. This approach represents a conceptually novel route to trifluoromethylated compounds that combines the insitu generation of the CF3 moiety and a CH functionalization in a single reaction system.
Subtype论文
Subject Area氟化学
DOI10.1002/anie.201409705
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000347238800046
Citation statistics
Cited Times:59[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39700
Collection中科院有机氟化学重点实验室
Corresponding AuthorHu JB(胡金波)
Affiliation中科院上海有机化学研究所, 有机氟化学重点实验室
Recommended Citation
GB/T 7714
Gao B,Zhao YC,Hu JB. AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones[J]. Angew. Chem.-Int. Edit.,2015,54(2):638-642.
APA 高兵,赵延川,&胡金波.(2015).AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones.Angew. Chem.-Int. Edit.,54(2),638-642.
MLA 高兵,et al."AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones".Angew. Chem.-Int. Edit. 54.2(2015):638-642.
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