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学科主题: 氟化学
题名: AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones
其他题名: 氟化银促进的双烯烃氟化交叉偶联反应: 一种便捷合成α-三氟甲基烯烃和 β-三氟甲基酮的方法
作者: Gao B(高兵); Zhao YC(赵延川); Hu JB(胡金波)
通讯作者: 胡金波
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201409705
卷: 54, 期:2, 页:638-642
收录类别: SCI
文章类型: 论文
英文摘要: A AgF-mediated fluorination with a concomitant cross-coupling between a gem-difluoroolefin and a non-fluorinated olefin is reported. This highly efficient method provides facile access to both -CF3 alkenes and -CF3 ketones, which otherwise remain challenging to be directly prepared. The application of this method is further demonstrated by the synthesis of bioactive isoxazoline derivatives. This approach represents a conceptually novel route to trifluoromethylated compounds that combines the insitu generation of the CF3 moiety and a CH functionalization in a single reaction system.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000347238800046
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39700
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 有机氟化学重点实验室

Recommended Citation:
Gao B,Zhao YC,Hu JB. AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones[J]. Angew. Chem.-Int. Edit.,2015,54(2):638-642.
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