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学科主题: 有机化学
题名: Copper-catalyzed trifluoromethylation of organic zinc reagents with an electrophilic trifluoromethylating reagent
其他题名: 铜催化的亲电三氟甲基化试剂与有机锌试剂的三氟甲基化反应
作者: Wang ZS(王长胜)1; Wang HY(王昊阳)1; Yao C(姚成)1
通讯作者: 姚成
刊名: RSC Adv.
发表日期: 2015
DOI: 10.1039/c5ra02279g
卷: 5, 期:31, 页:24783-24787
收录类别: SCI
文章类型: 论文
英文摘要: A copper-catalyzed trifluoromethylation of aryl, vinyl and alkyl zinc reagents with Togni's reagent was described. Mechanistic studies indicated that the aryl group is initially transferred from the zinc reagent to hypervalent iodine to form a tri-substituted hypervalent iodine intermediate. Consequent reductive-elimination via a concerted bond-forming step and/or radical pathway from this intermediate generates the trifluoromethylated arenes.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000351236300097
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39687
Appears in Collections:分析化学研究室_期刊论文

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作者单位: 1.南京工业大学
2.中科院上海有机化学研究所

Recommended Citation:
Wang ZS,Wang HY,Yao C. Copper-catalyzed trifluoromethylation of organic zinc reagents with an electrophilic trifluoromethylating reagent[J]. RSC Adv.,2015,5(31):24783-24787.
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