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学科主题: 金属有机化学
题名: Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives via Reactive Spiroindolenine Intermediates
其他题名: 含有三个连续手性中心的螺吲哚啉以及通过活性螺吲哚啉中间体对于色胺衍生物的不对称构建
作者: Zhuo CX(卓春祥)1; Zhou Y(周勇)1; Cheng Q(程强)1; Huang L(黄林)1; You SL(游书力)1
通讯作者: 游书力
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201507193
卷: 54, 期:47, 页:14146-14149
收录类别: SCI
文章类型: 论文
英文摘要: The highly efficient synthesis of the enantioenriched spiroindolines by iridium-catalyzed asymmetric allylic dearomatization and reduction is presented. Spiroindolines containing three contiguous stereogenic centers were obtained with excellent diastereo- and enantioselectivity. In addition, a chiral tryptamine derivative could be easily accessed in good yield with excellent ee value through an unprecedented dearomatization/retro-Mannich/hydrolysis cascade reaction of an indole derivative.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000367722500057
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39684
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心

Recommended Citation:
Zhuo CX,Zhou Y,Cheng Q,et al. Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives via Reactive Spiroindolenine Intermediates[J]. Angew. Chem.-Int. Edit.,2015,54(47):14146-14149.
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