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Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives via Reactive Spiroindolenine Intermediates
Alternative Title含有三个连续手性中心的螺吲哚啉以及通过活性螺吲哚啉中间体对于色胺衍生物的不对称构建
Zhuo CX(卓春祥)1; Zhou Y(周勇)1; Cheng Q(程强)1; Huang L(黄林)1; You SL(游书力)1
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:47Pages:14146-14149
AbstractThe highly efficient synthesis of the enantioenriched spiroindolines by iridium-catalyzed asymmetric allylic dearomatization and reduction is presented. Spiroindolines containing three contiguous stereogenic centers were obtained with excellent diastereo- and enantioselectivity. In addition, a chiral tryptamine derivative could be easily accessed in good yield with excellent ee value through an unprecedented dearomatization/retro-Mannich/hydrolysis cascade reaction of an indole derivative.
Subtype论文
Subject Area金属有机化学
DOI10.1002/anie.201507193
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000367722500057
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39684
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心
Recommended Citation
GB/T 7714
Zhuo CX,Zhou Y,Cheng Q,et al. Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives via Reactive Spiroindolenine Intermediates[J]. Angew. Chem.-Int. Edit.,2015,54(47):14146-14149.
APA 卓春祥,周勇,程强,黄林,&游书力.(2015).Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives via Reactive Spiroindolenine Intermediates.Angew. Chem.-Int. Edit.,54(47),14146-14149.
MLA 卓春祥,et al."Enantioselective Construction of Spiroindolines with Three Contiguous Stereogenic Centers and Chiral Tryptamine Derivatives via Reactive Spiroindolenine Intermediates".Angew. Chem.-Int. Edit. 54.47(2015):14146-14149.
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