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学科主题: 金属有机化学
题名: Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction
其他题名: 双功能硫脲催化的Michael反应实现β-萘酚的不对称去芳构化
作者: Wang SG(王守国)1; Liu XJ(刘喜佳)1; Zhao QC(赵群超)1; Zheng C(郑超)1; Wang SB(王少博)1; You SL(游书力)1
通讯作者: 游书力
刊名: Angew. Chem.-Int. Edit.
发表日期: 2015
DOI: 10.1002/anie.201507998
卷: 54, 期:49, 页:14929-14932
收录类别: SCI
文章类型: 论文
英文摘要: An intermolecular asymmetric dearomatization reaction of beta-naphthols with nitroethylene through a chiralthiourea-catalyzed Michael reaction is described. Enantioen-riched functionalized beta-naphthalenones with an all-carbon quaternary stereogenic center could thus be easily constructed from simple naphthol derivatives in good yields and excellent enantioselectivity (up to 79% yield, 98% ee).
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000367723400062
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39683
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心

Recommended Citation:
Wang SG,Liu XJ,Zhao QC,et al. Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction[J]. Angew. Chem.-Int. Edit.,2015,54(49):14929-14932.
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