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Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction
Alternative Title双功能硫脲催化的Michael反应实现β-萘酚的不对称去芳构化
Wang SG(王守国)1; Liu XJ(刘喜佳)1; Zhao QC(赵群超)1; Zheng C(郑超)1; Wang SB(王少博)1; You SL(游书力)1
2015
Source PublicationAngew. Chem.-Int. Edit.
Volume54Issue:49Pages:14929-14932
AbstractAn intermolecular asymmetric dearomatization reaction of beta-naphthols with nitroethylene through a chiralthiourea-catalyzed Michael reaction is described. Enantioen-riched functionalized beta-naphthalenones with an all-carbon quaternary stereogenic center could thus be easily constructed from simple naphthol derivatives in good yields and excellent enantioselectivity (up to 79% yield, 98% ee).
Subtype论文
Subject Area金属有机化学
DOI10.1002/anie.201507998
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000367723400062
Citation statistics
Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39683
Collection金属有机化学国家重点实验室
Corresponding AuthorYou SL(游书力)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心
Recommended Citation
GB/T 7714
Wang SG,Liu XJ,Zhao QC,et al. Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction[J]. Angew. Chem.-Int. Edit.,2015,54(49):14929-14932.
APA 王守国,刘喜佳,赵群超,郑超,王少博,&游书力.(2015).Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction.Angew. Chem.-Int. Edit.,54(49),14929-14932.
MLA 王守国,et al."Asymmetric Dearomatization of beta-Naphthols through a Bifunctional-Thiourea-Catalyzed Michael Reaction".Angew. Chem.-Int. Edit. 54.49(2015):14929-14932.
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