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学科主题: 金属有机化学
题名: Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes
其他题名: Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes
作者: CHEN CHAOHUANG; Chen PH(陈品红); Liu GS(刘国生)
通讯作者: 刘国生
刊名: J. Am. Chem. Soc.
发表日期: 2015
DOI: 10.1021/jacs.5b10971
卷: 137, 期:50, 页:15648-15651
收录类别: SCI
文章类型: 论文
英文摘要: The first catalytic trifluoromethoxylation of unactivated alkenes has been developed, in which Pd(CH3CN)(2)Cl-2 was used as catalyst, AgOCF3 as trifluoromethoxide source, and Selectfluor-BF4 as oxidant. A variety of 3-OCF3 substituted piperidines were selectively obtained in good yields. Direct evidence was provided to address the facile reductive elimination of Pe(IV)-OCF3 complex to form sp(3) C-OCF3 bond.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000367562800014
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39681
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
CHEN CHAOHUANG,Chen PH,Liu GS. Palladium-Catalyzed Intramolecular Aminotrifluoromethoxylation of Alkenes[J]. J. Am. Chem. Soc.,2015,137(50):15648-15651.
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