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Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration
Alternative Title利用钴催化的脱氢硼化-硼氢化, 从芳基乙烯基化合物合成1,1,1-三硼酸酯
Zhang L(张雷); Huang Z(黄正)
2015
Source PublicationJ. Am. Chem. Soc.
Volume137Issue:50Pages:15600-15603
AbstractThe selective preparation of 1,1,1-tris-(boronates) from vinylarenes and bis(pinacolato)diboron is described. The reactions occur at ambient temperature with excellent selectivity, high yields, and good functional group tolerance. Mechanistic studies suggest that Co(I)-catalyzed double dehydrogenative borylations generate a 1,1-diborylalkene intermediate, which undergoes hydroboration with pinacolborane formed in situ to yield 1,1,1-tris (boronate).
Subtype论文
Subject Area金属有机化学
DOI10.1021/jacs.5b11366
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000367562800002
Citation statistics
Cited Times:46[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39680
Collection金属有机化学国家重点实验室
Corresponding AuthorHuang Z(黄正)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Zhang L,Huang Z. Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration[J]. J. Am. Chem. Soc.,2015,137(50):15600-15603.
APA 张雷,&黄正.(2015).Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration.J. Am. Chem. Soc.,137(50),15600-15603.
MLA 张雷,et al."Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration".J. Am. Chem. Soc. 137.50(2015):15600-15603.
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