中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration
其他题名: 利用钴催化的脱氢硼化-硼氢化, 从芳基乙烯基化合物合成1,1,1-三硼酸酯
作者: Zhang L(张雷); Huang Z(黄正)
通讯作者: 黄正
刊名: J. Am. Chem. Soc.
发表日期: 2015
DOI: 10.1021/jacs.5b11366
卷: 137, 期:50, 页:15600-15603
收录类别: SCI
文章类型: 论文
英文摘要: The selective preparation of 1,1,1-tris-(boronates) from vinylarenes and bis(pinacolato)diboron is described. The reactions occur at ambient temperature with excellent selectivity, high yields, and good functional group tolerance. Mechanistic studies suggest that Co(I)-catalyzed double dehydrogenative borylations generate a 1,1-diborylalkene intermediate, which undergoes hydroboration with pinacolborane formed in situ to yield 1,1,1-tris (boronate).
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000367562800002
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39680
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015691.pdf(1058KB)期刊论文作者接受稿开放获取View Download

作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Zhang L,Huang Z. Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations-Hydroboration[J]. J. Am. Chem. Soc.,2015,137(50):15600-15603.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[张雷]'s Articles
[黄正]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[张雷]‘s Articles
[黄正]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015691.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace