SIOC OpenIR  > 金属有机化学国家重点实验室
The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide
Alternative Title高对映选择性的2-炔基溴和二氧化碳的羧化反应
缪不可言1; Li G(李根)1; Ma SM(麻生明)1
2015
Source PublicationChem.-Eur. J.
Volume21Issue:48Pages:17224-17228
AbstractA steric effect-controlled, zinc-mediated carboxylation of different 2-alkynyl bromides under an atmospheric pressure of CO2 has been developed by careful tuning of different reaction parameters, including the metal, solvent, temperature, and additive. 2-Substituted 2,3-allenoic acids were afforded from primary 2-alkynyl bromides, whereas the carboxylation of secondary 2-alkynyl bromides yielded 3-alkynoic acids in decent yields. A rationale for the observed regioselectivity has been proposed.
Subtype论文
Subject Area金属有机化学
DOI10.1002/chem.201503494
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000366510900012
Citation statistics
Cited Times:11[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39677
Collection金属有机化学国家重点实验室
Corresponding AuthorMa SM(麻生明)
Affiliation1.华东师范大学
2.复旦大学
3.中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
缪不可言,Li G,Ma SM. The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide[J]. Chem.-Eur. J.,2015,21(48):17224-17228.
APA 缪不可言,李根,&麻生明.(2015).The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide.Chem.-Eur. J.,21(48),17224-17228.
MLA 缪不可言,et al."The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide".Chem.-Eur. J. 21.48(2015):17224-17228.
Files in This Item:
File Name/Size DocType Version Access License
2015671.pdf(642KB)期刊论文作者接受稿开放获取CC BY-NC-SAApplication Full Text
Related Services
Recommend this item
Bookmark
Usage statistics
Export to Endnote
Google Scholar
Similar articles in Google Scholar
[缪不可言]'s Articles
[李根]'s Articles
[麻生明]'s Articles
Baidu academic
Similar articles in Baidu academic
[缪不可言]'s Articles
[李根]'s Articles
[麻生明]'s Articles
Bing Scholar
Similar articles in Bing Scholar
[缪不可言]'s Articles
[李根]'s Articles
[麻生明]'s Articles
Terms of Use
No data!
Social Bookmark/Share
All comments (0)
No comment.
 

Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.