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学科主题: 金属有机化学
题名: Gold-Catalyzed Synthesis of Tropone and Its Analogues via Oxidative Ring Expansion of Alkynyl Quinols
其他题名: 金催化炔基对苯二酚的氧化扩环反应: 环庚三烯酮及其类似物的合成
作者: Zhao JD(赵继东); Liu J(刘俊); Jie X(解鑫); Li S(李石); Liu YH(刘元红)
通讯作者: 李石 ; 刘元红
刊名: Org. Lett.
发表日期: 2015
DOI: 10.1021/acs.orglett.5b03160
卷: 17, 期:23, 页:5926-5929
收录类别: SCI
文章类型: 论文
英文摘要: A new and convenient strategy for the synthesis of functionalized tropone derivatives based on the gold-catalyzed oxidative ring expansion of alkynyl quinols has been developed. The reaction proceeds via gold-catalyzed highly regioselective oxidation followed by 1,2-migration of a vinyl or phenyl group. Extension of this chemistry allows ready access to various seven- or six-membered ring systems such as benzotropones, benzooxepines, phenanthrenes, and quinolin-2(1H)-ones.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000366152000052
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39674
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Zhao JD,Liu J,Jie X,et al. Gold-Catalyzed Synthesis of Tropone and Its Analogues via Oxidative Ring Expansion of Alkynyl Quinols[J]. Org. Lett.,2015,17(23):5926-5929.
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