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Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones
Alternative Title手性膦催化的高区域和高对映选择性环化反应研究-构建螺环骨架的苯并呋喃类化合物
Wang D(王德)1; Wang GP(王国鹏)1; Sun YL(孙姚良)1; Zhu SF(朱守非)1; Wei Y(魏音)1; Zhou QL(周其林)1; Shi M(施敏)1
2015
Source PublicationChem. Sci.
Volume6Issue:12Pages:7319-7325
AbstractThe first regioselective catalytic asymmetric [3 + 2] cycloaddition of benzofuranone-derived olefins with allenoates and substituted allenoates has been developed in the presence of (R)-SITCP, affording different functionalized 3-spirocyclopentene benzofuran-2-ones in good yields with high enantioselectivities under mild conditions. The substrate scope has also been examined. The regioselective outcomes for this phosphine-catalyzed [3 + 2] cycloaddition reaction can be rationalized using DFT calculations.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c5sc03135d
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000365225300076
Citation statistics
Cited Times:43[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39672
Collection金属有机化学国家重点实验室
Corresponding AuthorWei Y(魏音); Zhou QL(周其林); Shi M(施敏)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.南开大学
Recommended Citation
GB/T 7714
Wang D,Wang GP,Sun YL,et al. Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones[J]. Chem. Sci.,2015,6(12):7319-7325.
APA 王德.,王国鹏.,孙姚良.,朱守非.,魏音.,...&施敏.(2015).Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones.Chem. Sci.,6(12),7319-7325.
MLA 王德,et al."Chiral phosphine-catalyzed tunable cycloaddition reactions of allenoates with benzofuranone-derived olefins for a highly regio-, diastereo- and enantioselective synthesis of spiro-benzofuranones".Chem. Sci. 6.12(2015):7319-7325.
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