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学科主题: 金属有机化学
题名: Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy
其他题名: 用混合配体策略抑制铑(I)催化β-芳氧基丙烯酸不对称氢化中的芳氧消除
作者: Li Y(李洋)1; Wang Z(王正)1; Ding KL(丁奎岭)1
通讯作者: 丁奎岭
刊名: Chem.-Eur. J.
发表日期: 2015
DOI: 10.1002/chem.201503229
卷: 21, 期:46, 页:16387-16390
收录类别: SCI
文章类型: 论文
英文摘要: The first example of efficient asymmetric hydrogenation of challenging -aryloxyacrylic acids was realized using a Rh-I-complex based on the heterocombination of a readily available chiral monodentate secondary phosphine oxide (SPO) and an achiral monodentate phosphine ligand as the catalyst. Excellent enantioselectivities (92->99% ee) were achieved for a wide variety of chiral -aryloxypropionic acids with minor aryloxy elimination in most cases. The resultant products were readily transformed into biologically active compounds through simple synthetic manipulations.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000365132100014
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39670
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心

Recommended Citation:
Li Y,Wang Z,Ding KL. Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy[J]. Chem.-Eur. J.,2015,21(46):16387-16390.
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