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Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy
Alternative Title用混合配体策略抑制铑(I)催化β-芳氧基丙烯酸不对称氢化中的芳氧消除
Li Y(李洋)1; Wang Z(王正)1; Ding KL(丁奎岭)1
2015
Source PublicationChem.-Eur. J.
Volume21Issue:46Pages:16387-16390
AbstractThe first example of efficient asymmetric hydrogenation of challenging -aryloxyacrylic acids was realized using a Rh-I-complex based on the heterocombination of a readily available chiral monodentate secondary phosphine oxide (SPO) and an achiral monodentate phosphine ligand as the catalyst. Excellent enantioselectivities (92->99% ee) were achieved for a wide variety of chiral -aryloxypropionic acids with minor aryloxy elimination in most cases. The resultant products were readily transformed into biologically active compounds through simple synthetic manipulations.
Subtype论文
Subject Area金属有机化学
DOI10.1002/chem.201503229
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000365132100014
Citation statistics
Cited Times:7[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39670
Collection金属有机化学国家重点实验室
Corresponding AuthorDing KL(丁奎岭)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.天津化学化工协同创新中心
Recommended Citation
GB/T 7714
Li Y,Wang Z,Ding KL. Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy[J]. Chem.-Eur. J.,2015,21(46):16387-16390.
APA 李洋,王正,&丁奎岭.(2015).Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy.Chem.-Eur. J.,21(46),16387-16390.
MLA 李洋,et al."Minimizing Aryloxy Elimination in Rh-I-Catalyzed Asymmetric Hydrogenation of -Aryloxyacrylic Acids using a Mixed-Ligand Strategy".Chem.-Eur. J. 21.46(2015):16387-16390.
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