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Selectfluor promoted NHC-oxazoline gold(I) complex catalyzed cycloaddition/oxidation reaction of enynones with alkenes
其他题名氮杂环卡宾和恶唑啉的三价金配合物用于炔酮和烯烃的氧化/环加成反应
Xu Q(徐琴)1; Gu P(古鹏)1; Wang FJ(王飞军)1; Shi M(施敏)1
2015
发表期刊Org. Chem. Front.
卷号2期号:11页码:1475-1484
摘要The ortho- and meta-substituted NHC-oxazoline ligands based on a phenyl scaffold have been synthesized in a six-step pathway, and their coordination with Au(Me2S)Cl gave the corresponding NHC-gold(I) complexes in good yields. Resulting from restricted rotation between the phenyl ring and the benzimidazole ring, the ortho-substituted NHC-oxazoline gold(I) complexes exhibited as a pair of diastereomers, and their structures have been further confirmed by X-ray diffraction analysis. Moreover, combination of these gold(I) complexes with Selectfluor in situ was used to catalyze the reaction of enynone with alkenes using air as an oxidant to give naphthalene derivatives in moderate to excellent yields. Some controlled experiments were carried out to reveal the active species as a chelated NHC-oxazoline gold(I) species and the role Selecfluor played in this reaction.
文章类型论文
学科领域金属有机化学
DOI10.1039/c5qo00155b
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000364450200006
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被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/39668
专题金属有机化学国家重点实验室
通讯作者Wang FJ(王飞军); Shi M(施敏)
作者单位1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.华东理工大学
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Xu Q,Gu P,Wang FJ,et al. Selectfluor promoted NHC-oxazoline gold(I) complex catalyzed cycloaddition/oxidation reaction of enynones with alkenes[J]. Org. Chem. Front.,2015,2(11):1475-1484.
APA 徐琴,古鹏,王飞军,&施敏.(2015).Selectfluor promoted NHC-oxazoline gold(I) complex catalyzed cycloaddition/oxidation reaction of enynones with alkenes.Org. Chem. Front.,2(11),1475-1484.
MLA 徐琴,et al."Selectfluor promoted NHC-oxazoline gold(I) complex catalyzed cycloaddition/oxidation reaction of enynones with alkenes".Org. Chem. Front. 2.11(2015):1475-1484.
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