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Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization
Alternative Title利用不对称环化反应高效合成P-手性联芳基磷酸酯的方法
Xu GQ(徐广庆); Li MH(李明洪); Wang SL(王守亮); Tang WJ(汤文军)
2015
Source PublicationOrg. Chem. Front.
Volume2Issue:10Pages:1342-1345
AbstractA series of P-chiral biaryl phosphonates were efficiently synthesized from diaryl 2-bromo arylphosphonates in high yields (up to 92%) and good enantioselectivities (up to 88% ee) through a palladium-catalyzed asymmetric cyclization with a novel P-chiral biaryl monophosphorus ligand. The P-chiral biaryl phosphonate can be rapidly transformed to both antipodes of a P-chiral dialkyl biaryl monophosphorus structure. The method provides a convenient access to various P-chiral biaryl monophosphines.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c5qo00142k
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364450000008
Citation statistics
Cited Times:22[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39667
Collection金属有机化学国家重点实验室
Corresponding AuthorTang WJ(汤文军)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Xu GQ,Li MH,Wang SL,et al. Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization[J]. Org. Chem. Front.,2015,2(10):1342-1345.
APA 徐广庆,李明洪,王守亮,&汤文军.(2015).Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization.Org. Chem. Front.,2(10),1342-1345.
MLA 徐广庆,et al."Efficient synthesis of P-chiral biaryl phosphonates by stereoselective intramolecular cyclization".Org. Chem. Front. 2.10(2015):1342-1345.
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