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学科主题: 金属有机化学
题名: Enantioselective nickel-catalyzed alkylative alkyne-aldehyde cross-couplings
其他题名: 对映选择性镍催化烷基化炔醛偶联
作者: Nie M(聂明); Fu WZ(付文振); Cao ZP(曹子平); Tang WJ(汤文军)
通讯作者: 汤文军
刊名: Org. Chem. Front.
发表日期: 2015
DOI: 10.1039/c5qo00148j
卷: 2, 期:10, 页:1322-1325
收录类别: SCI
文章类型: 论文
英文摘要: An efficient asymmetric nickel-catalyzed alkylative alkyne-aldehyde cross-coupling is developed by employing a P-chiral monophosphorus ligand BI-DIME, allowing rapid access to a series of chiral tetra-substituted olefinic allylic alcohols in high yields and good to excellent ees. The three-component reactions enjoy excellent regio- and enantioselectivities, and a broad substrate scope from readily available starting materials.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364450000004
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39666
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 生命有机化学国家重点实验室

Recommended Citation:
Nie M,Fu WZ,Cao ZP,et al. Enantioselective nickel-catalyzed alkylative alkyne-aldehyde cross-couplings[J]. Org. Chem. Front.,2015,2(10):1322-1325.
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