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Enantioselective nickel-catalyzed alkylative alkyne-aldehyde cross-couplings
Alternative Title对映选择性镍催化烷基化炔醛偶联
Nie M(聂明); Fu WZ(付文振); Cao ZP(曹子平); Tang WJ(汤文军)
Source PublicationOrg. Chem. Front.
AbstractAn efficient asymmetric nickel-catalyzed alkylative alkyne-aldehyde cross-coupling is developed by employing a P-chiral monophosphorus ligand BI-DIME, allowing rapid access to a series of chiral tetra-substituted olefinic allylic alcohols in high yields and good to excellent ees. The three-component reactions enjoy excellent regio- and enantioselectivities, and a broad substrate scope from readily available starting materials.
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000364450000004
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorTang WJ(汤文军)
Affiliation中科院上海有机化学研究所, 生命有机化学国家重点实验室
Recommended Citation
GB/T 7714
Nie M,Fu WZ,Cao ZP,et al. Enantioselective nickel-catalyzed alkylative alkyne-aldehyde cross-couplings[J]. Org. Chem. Front.,2015,2(10):1322-1325.
APA 聂明,付文振,曹子平,&汤文军.(2015).Enantioselective nickel-catalyzed alkylative alkyne-aldehyde cross-couplings.Org. Chem. Front.,2(10),1322-1325.
MLA 聂明,et al."Enantioselective nickel-catalyzed alkylative alkyne-aldehyde cross-couplings".Org. Chem. Front. 2.10(2015):1322-1325.
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