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学科主题: 金属有机化学
题名: Solvent-controlled nucleophilic trifluoromethylthiolation of Morita-Baylis-Hillman carbonates: dual roles of DABCO in activating the Zard's trifluoromethylthiolation reagent and the MBH carbonates
其他题名: 溶剂控制的MBH反应产物的亲核硫三氟甲基化反应: DABCO的双重活化作用
作者: Yang HB(杨海斌); Fan X(樊星); Wei Y(魏音); Shi M(施敏)
通讯作者: 魏音 ; 施敏
刊名: Org. Chem. Front.
发表日期: 2015
DOI: 10.1039/c5qo00198f
卷: 2, 期:9, 页:1088-1093
收录类别: SCI
文章类型: 论文
英文摘要: A novel amine-catalyzed nucleophilic trifluoromethylthiolation between Morita-Baylis-Hillman carbonates and O-octadecyl-S-trifluorothiolcarbonate has been developed. The regioselectivity of this reaction can be controlled by choosing different solvents, affording primary allylic SCF3 products in THF and secondary allylic SCF3 products in CHCl3 as major products. The mechanistic investigation indicated that DABCO plays a dual role in activating the Zard's trifluoromethylthiolation reagent and the MBH carbonates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364449800018
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39665
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Yang HB,Fan X,Wei Y,et al. Solvent-controlled nucleophilic trifluoromethylthiolation of Morita-Baylis-Hillman carbonates: dual roles of DABCO in activating the Zard's trifluoromethylthiolation reagent and the MBH carbonates[J]. Org. Chem. Front.,2015,2(9):1088-1093.
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