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Palladium-catalyzed intramolecular rearrangement of vinylidenecyclopropanes through C-C bond activation
Alternative Title金属钯催化的亚乙烯基环丙烷的分子内重排反应
Pan D(潘东); Chen GQ(陈根强); Tang XY(唐翔鹰); Shi M(施敏)
2015
Source PublicationOrg. Chem. Front.
Volume2Issue:7Pages:792-796
AbstractVinylidenecyclopropanes bearing sulfonamide can undergo a novel intramolecular rearrangement to give the corresponding functionalized dimethylenecyclopropanes in moderate to good yields in the presence of Pd(OAc)(2) in toluene upon heating through C-C bond activation based on weak coordination of the sulfonamide directing group. The reaction pathway can be changed for phenyl substituted vinylidenecyclopropane, giving another type of dimethylenecyclopropane in methanol in the presence of K2CO3 under reflux.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c5qo00127g
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364448400006
Citation statistics
Cited Times:4[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39662
Collection金属有机化学国家重点实验室
Corresponding AuthorShi M(施敏)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Pan D,Chen GQ,Tang XY,et al. Palladium-catalyzed intramolecular rearrangement of vinylidenecyclopropanes through C-C bond activation[J]. Org. Chem. Front.,2015,2(7):792-796.
APA 潘东,陈根强,唐翔鹰,&施敏.(2015).Palladium-catalyzed intramolecular rearrangement of vinylidenecyclopropanes through C-C bond activation.Org. Chem. Front.,2(7),792-796.
MLA 潘东,et al."Palladium-catalyzed intramolecular rearrangement of vinylidenecyclopropanes through C-C bond activation".Org. Chem. Front. 2.7(2015):792-796.
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