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学科主题: 金属有机化学
题名: Palladium-catalyzed intramolecular rearrangement of vinylidenecyclopropanes through C-C bond activation
其他题名: 金属钯催化的亚乙烯基环丙烷的分子内重排反应
作者: Pan D(潘东); Chen GQ(陈根强); Tang XY(唐翔鹰); Shi M(施敏)
通讯作者: 施敏
刊名: Org. Chem. Front.
发表日期: 2015
DOI: 10.1039/c5qo00127g
卷: 2, 期:7, 页:792-796
收录类别: SCI
文章类型: 论文
英文摘要: Vinylidenecyclopropanes bearing sulfonamide can undergo a novel intramolecular rearrangement to give the corresponding functionalized dimethylenecyclopropanes in moderate to good yields in the presence of Pd(OAc)(2) in toluene upon heating through C-C bond activation based on weak coordination of the sulfonamide directing group. The reaction pathway can be changed for phenyl substituted vinylidenecyclopropane, giving another type of dimethylenecyclopropane in methanol in the presence of K2CO3 under reflux.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364448400006
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39662
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所, 金属有机化学国家重点实验室

Recommended Citation:
Pan D,Chen GQ,Tang XY,et al. Palladium-catalyzed intramolecular rearrangement of vinylidenecyclopropanes through C-C bond activation[J]. Org. Chem. Front.,2015,2(7):792-796.
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