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学科主题: 金属有机化学
题名: CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes
其他题名: CuBr2催化的对映选择性合成高官能团化的天然产物联烯的方法
作者: Tang XJ(汤鑫军)1; Huang X(黄鑫)1; Cao T(曹陶)1; Han YL(韩玉林)1; Jiang XG(姜兴国)1; Lin WL(林渭龙)1; Tang Y(唐阳)1; Zhang JS(张加生)1; Yu Q(俞琼)1; Fu CL(傅春玲)1; Ma SM(麻生明)1
通讯作者: 麻生明
刊名: Org. Chem. Front.
发表日期: 2015
DOI: 10.1039/c5qo00084j
卷: 2, 期:6, 页:688-691
收录类别: SCI
文章类型: 论文
英文摘要: Here we show the CuBr2-catalyzed approach for highly enantioselective synthesis (90-98% ee) of allenes bearing a very broad array of unmasked synthetically attractive functionalities from aldehydes and terminal alkynyl bearing reactive functionalities with the absolute configuration controlled by applying readily available (R)- or ( S)-alpha,alpha-diphenylprolinol. Following this protocol, the highly enantioselective synthesis of some naturally occurring allenes loaded with reactive functionalities becomes simple: a terminal alkyne plus an aldehyde. In comparison, they were reported to be synthesized either from similar level generic chemicals with much more steps or in lower ees.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364445900012
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39661
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.浙江大学
3.华东师范大学

Recommended Citation:
Tang XJ,Huang X,Cao T,et al. CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes[J]. Org. Chem. Front.,2015,2(6):688-691.
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