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CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes
Alternative TitleCuBr2催化的对映选择性合成高官能团化的天然产物联烯的方法
Tang XJ(汤鑫军)1; Huang X(黄鑫)1; Cao T(曹陶)1; Han YL(韩玉林)1; Jiang XG(姜兴国)1; Lin WL(林渭龙)1; Tang Y(唐阳)1; Zhang JS(张加生)1; Yu Q(俞琼)1; Fu CL(傅春玲)1; Ma SM(麻生明)1
2015
Source PublicationOrg. Chem. Front.
Volume2Issue:6Pages:688-691
AbstractHere we show the CuBr2-catalyzed approach for highly enantioselective synthesis (90-98% ee) of allenes bearing a very broad array of unmasked synthetically attractive functionalities from aldehydes and terminal alkynyl bearing reactive functionalities with the absolute configuration controlled by applying readily available (R)- or ( S)-alpha,alpha-diphenylprolinol. Following this protocol, the highly enantioselective synthesis of some naturally occurring allenes loaded with reactive functionalities becomes simple: a terminal alkyne plus an aldehyde. In comparison, they were reported to be synthesized either from similar level generic chemicals with much more steps or in lower ees.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c5qo00084j
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364445900012
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39661
Collection金属有机化学国家重点实验室
Corresponding AuthorMa SM(麻生明)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.浙江大学
3.华东师范大学
Recommended Citation
GB/T 7714
Tang XJ,Huang X,Cao T,et al. CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes[J]. Org. Chem. Front.,2015,2(6):688-691.
APA 汤鑫军.,黄鑫.,曹陶.,韩玉林.,姜兴国.,...&麻生明.(2015).CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes.Org. Chem. Front.,2(6),688-691.
MLA 汤鑫军,et al."CuBr2-catalyzed enantioselective routes to highly functionalized and naturally occurring allenes".Org. Chem. Front. 2.6(2015):688-691.
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