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Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines
Alternative Title二碘化锌促进的从丙炔胺出发合成三取代联烯的方法
Kuang JQ(况锦强)1; Tang XJ(汤鑫军)1; Ma SM(麻生明)1
2015
Source PublicationOrg. Chem. Front.
Volume2Issue:5Pages:470-475
AbstractZinc diiodide has been identified as an effective reagent for the efficient synthesis of trisubstituted allenes from propargylic amines. Compared to CdI2 this protocol offers a green approach. Due to the easy preparation of propargylic amines through the method developed by this group, this method provides a two-step synthesis of trisubstituted allenes from 1-alkynes, ketones, and pyrrolidine. Finally, an efficient synthesis of such trisubstituted allenes from 1-alkynes, ketones, and pyrrolidine via simple filtration has been developed. Compared with the CdI2-mediated protocol, the current protocol enjoys a much wider scope for ketones and affords functionalized allenes without further cyclization in some substrates.
Subtype论文
Subject Area金属有机化学
DOI10.1039/c5qo00047e
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364445300003
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39659
Collection金属有机化学国家重点实验室
Corresponding AuthorMa SM(麻生明)
Affiliation1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.复旦大学
Recommended Citation
GB/T 7714
Kuang JQ,Tang XJ,Ma SM. Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines[J]. Org. Chem. Front.,2015,2(5):470-475.
APA 况锦强,汤鑫军,&麻生明.(2015).Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines.Org. Chem. Front.,2(5),470-475.
MLA 况锦强,et al."Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines".Org. Chem. Front. 2.5(2015):470-475.
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