中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines
其他题名: 二碘化锌促进的从丙炔胺出发合成三取代联烯的方法
作者: Kuang JQ(况锦强)1; Tang XJ(汤鑫军)1; Ma SM(麻生明)1
通讯作者: 麻生明
刊名: Org. Chem. Front.
发表日期: 2015
DOI: 10.1039/c5qo00047e
卷: 2, 期:5, 页:470-475
收录类别: SCI
文章类型: 论文
英文摘要: Zinc diiodide has been identified as an effective reagent for the efficient synthesis of trisubstituted allenes from propargylic amines. Compared to CdI2 this protocol offers a green approach. Due to the easy preparation of propargylic amines through the method developed by this group, this method provides a two-step synthesis of trisubstituted allenes from 1-alkynes, ketones, and pyrrolidine. Finally, an efficient synthesis of such trisubstituted allenes from 1-alkynes, ketones, and pyrrolidine via simple filtration has been developed. Compared with the CdI2-mediated protocol, the current protocol enjoys a much wider scope for ketones and affords functionalized allenes without further cyclization in some substrates.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364445300003
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39659
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2015598.pdf(350KB)期刊论文作者接受稿开放获取View Download

作者单位: 1.中科院上海有机化学研究所, 金属有机化学国家重点实验室
2.复旦大学

Recommended Citation:
Kuang JQ,Tang XJ,Ma SM. Zinc diiodide-promoted synthesis of trisubstituted allenes from propargylic amines[J]. Org. Chem. Front.,2015,2(5):470-475.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[况锦强]'s Articles
[汤鑫军]'s Articles
[麻生明]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[况锦强]‘s Articles
[汤鑫军]‘s Articles
[麻生明]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2015598.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace