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学科主题: 金属有机化学
题名: Zinc-mediated allylation of carbon dioxide-the LiOAc effect
其他题名: 锌促进的二氧化碳的烯丙基化反应-LiOAc的作用
作者: 缪不可言1; Ma SM(麻生明)1
通讯作者: 麻生明
刊名: Org. Chem. Front.
发表日期: 2015
DOI: 10.1039/c4qo00300d
卷: 2, 期:1, 页:65-68
收录类别: SCI
文章类型: 论文
英文摘要: A direct carboxylation reaction of allylic bromides mediated by zinc powder has been developed. The reaction occurred smoothly at room temperature with 1 atm of CO2 provided by a balloon. The reaction was conducted in the presence of LiOAc giving excellent yields. An excellent branched regioselectivity was observed and the reaction was easily scaled-up to 10 gram-scale.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000364442500013
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39657
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 1.华东师范大学
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
3.复旦大学

Recommended Citation:
缪不可言,Ma SM. Zinc-mediated allylation of carbon dioxide-the LiOAc effect[J]. Org. Chem. Front.,2015,2(1):65-68.
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