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Zinc-mediated allylation of carbon dioxide-the LiOAc effect
Alternative Title锌促进的二氧化碳的烯丙基化反应-LiOAc的作用
缪不可言1; Ma SM(麻生明)1
Source PublicationOrg. Chem. Front.
AbstractA direct carboxylation reaction of allylic bromides mediated by zinc powder has been developed. The reaction occurred smoothly at room temperature with 1 atm of CO2 provided by a balloon. The reaction was conducted in the presence of LiOAc giving excellent yields. An excellent branched regioselectivity was observed and the reaction was easily scaled-up to 10 gram-scale.
Subject Area金属有机化学
Indexed BySCI
WOS IDWOS:000364442500013
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Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Corresponding AuthorMa SM(麻生明)
2.中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
缪不可言,Ma SM. Zinc-mediated allylation of carbon dioxide-the LiOAc effect[J]. Org. Chem. Front.,2015,2(1):65-68.
APA 缪不可言,&麻生明.(2015).Zinc-mediated allylation of carbon dioxide-the LiOAc effect.Org. Chem. Front.,2(1),65-68.
MLA 缪不可言,et al."Zinc-mediated allylation of carbon dioxide-the LiOAc effect".Org. Chem. Front. 2.1(2015):65-68.
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