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学科主题: 有机化学
题名: 铝盐促进的谷氨酸转氨化合成α-酮戊二酸的研究
其他题名: Aluminum(III) Salts Promoted Transamination of Glutamic Acid for the Synthesis of alpha-Ketoglutaric Acid
作者: 吴江; 黄少胥
通讯作者: 黄少胥
刊名: 有机化学
发表日期: 2015
DOI: 10.6023/cjoc201504041
卷: 35, 期:9, 页:1991-1993
收录类别: SCI
文章类型: 论文
英文摘要: This paper reports an efficient approach for the synthesis of a-ketoglutaric acid via Al(III) salt promoted transamination of glyoxylic acid monohydrate with glutamic acid. Under optimized conditions (80 degrees C, pH=5), the transamination proceeded efficiently in an aqueous solution of glyoxylic acid and glutamic acid in the presence of a catalytic amount of KAl(SO4)(2)center dot 12H(2)O, affording a-ketoglutaric acid in up to 87% yield. This method features inexpensive chemical feedstocks, easy operation and high productivity, thus providing an efficient and practical approach to a-ketoglutaric acid.
语种: 中文
相关网址: 查看原文
WOS记录号: WOS:000364618100021
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/39655
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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作者单位: 中科院上海有机化学研究所

Recommended Citation:
吴江,黄少胥. 铝盐促进的谷氨酸转氨化合成α-酮戊二酸的研究[J]. 有机化学,2015,35(9):1991-1993.
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