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Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis
Alternative Title铬催化的不对称合成α亚甲基γ丁内酯
Chen WQ(陈伟强); Yang Q(杨琴); Zhou T(周添); Tian QS(田青杉); Zhang GZ(张国柱)
2015
Source PublicationOrg. Lett.
Volume17Issue:21Pages:5236-5239
AbstractEnantioenriched alpha-exo-methylene gamma-butyrolactones have been obtained via a two-step sequence consisting of a highly enantioselective chromium-catalyzed carbonyl 2-(alkoxycarbonyl)allylation and lactonization. A variety of functional groups are compatible under the mild reaction conditions. The synthetic utility of this methodology was demonstrated by two short derivatization transformations and the enantioselective synthesis of (+)-methylenolactocin.
Subtype论文
Subject Area金属有机化学
DOI10.1021/acs.orglett.5b02597
URL查看原文
Indexed BySCI
Language英语
WOS IDWOS:000364434900023
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Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/39653
Collection金属有机化学国家重点实验室
Corresponding AuthorZhang GZ(张国柱)
Affiliation中科院上海有机化学研究所, 金属有机化学国家重点实验室
Recommended Citation
GB/T 7714
Chen WQ,Yang Q,Zhou T,et al. Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis[J]. Org. Lett.,2015,17(21):5236-5239.
APA 陈伟强,杨琴,周添,田青杉,&张国柱.(2015).Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis.Org. Lett.,17(21),5236-5239.
MLA 陈伟强,et al."Enantioselective Synthesis of alpha-exo-Methylene gamma-Butyrolactones via Chromium Catalysis".Org. Lett. 17.21(2015):5236-5239.
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